Chromium is one of the 25 most widespread elements in the Earth’s crust and occurs as an indelible non-volatile trace element in raw materials used in cement clinker production (clay, limestone and iron additives in particular). Chromium in raw materials mentioned above is mainly in form of trivalent chromium. Naturally occurring chromium (III) is not initially harmful, since it is chemically s...

BACKGROUND Chromium (VI) has toxic and carcinogenic effects. So, determination and speciation of chromium in environmental samples is very important in view of health hazards. In this study, solid phase extraction (SPE) based on bulky amine-functionalized bimodal mesoporous silica nanoparticles (NH2-UVM-7) as a novel nanoadsorbent was applied for preconcentration and speciation of chromium (III...

Chromium exists in many different oxidation states in the environment, Cr(VI) and Cr(III) being the most stable forms. Chromium has been known for over 100 years to be a human carcinogen. The greatest risk of cancer from chromium exposure is associated with Cr(VI). Cr(VI) enters cells via the sulfate anion transporter system and is reduced to intermediate oxidation states, such as Cr(V) and Cr(...

The potential to remove chromium(VI) from aqueous solutions through biosorption using coffee husk was investigated. The effects of pH, contact time, initial concentration and adsorbent dosage on the adsorption of Cr(VI) were studied. The data obeyed Langmuir and Freundlich adsorption isotherms. The Langmuir adsorption capacity was found to be 44.95 mg/g. The Freundlich constants Kf and n were 1...

Title of dissertation: USE OF TARTARIC ACID AND ISOPROPYL ALCOHOL IN THE REDUCTION OF HEXAVALENT CHROMIUM AND APPLICATION TO CHROMIUM CONTAMINATED SOILS AND CHROMITE ORE PROCESSING RESIDUE Dominic A. Brose, Doctor of Philosophy, 2012 Dissertation directed by: Professor Bruce R. James Department of Environmental Science and Technology Although chromium (Cr) is a naturally occurring metal, in the...

The increasing industrial development of recent decades has lead to the production of increasing quantities of waste containing heavy metals, elements often harmful to the environment, which in the past were not properly disposed of, thus inducing soil and groundwater pollution. In particular, chromium (Cr) and its derivatives are largely used in industries such as textiles, electronics, metall...

An evaluation of the chromium(VI) adsorption capacity of four magnetite sorbents coated with a polymer phase containing polymethacrylic acid or polyallyl-3-methylimidazolium is presented. Factors that influence the chromium(VI) removal such as solution pH and contact time were investigated in batch experiments and in stirred tank reactor mode. Affinity and rate constants increased with the mola...

High levels of hexavalent chromium (Cr(VI)) in groundwater are typically attributed to anthropogenic sources. However, scientific reports over the last decade have demonstrated that relatively high levels of Cr(VI) in groundwater may also be due to natural processes. Cr(VI) is among the most significant groundwater contaminants, since it is a potential carcinogenic compound that is commonly fou...

Effects of water contamination with perchlorate and hexavalent chromium [Cr (VI)] on the mosquito Culex quinquefasciatus were assessed. The chronic (10-day) LC50s values for perchlorate and chromium were 74+/-8.0 mg/L and 0.41+/-0.15 mg/L, respectively. Relative Growth Index, a measure of growth and mortality rates in a population, was significantly reduced within 5 days for levels of perchlora...