In the title compound, [Cr(C(29)H(30)P(2))(CO)(4)], the Cr atom is octa-hedrally coordinated by four carbonyl ligands and one bidentate phosphine ligand, which is bounded as a chelate in a cis position. The average Cr-P and Cr-C bond lengths are 2.377 and 1.865 Å, respectively.

BACKGROUND Chromium picolinate (Cr(pic)3) is advocated as adjuvant therapy for impaired glycemic control, despite concerns for DNA damage. Potential toxicity of Cr(pic)3 should be greater for the kidney that accumulates chromium. Therefore, we tested the hypothesis that Cr(pic)3 treatment of obese Zucker rats (OZR) exacerbates renal abnormalities associated with dysglycemia. METHODS Male OZR ...

Absorptive characteristics of polyaniline synthesized in mixture of water and acetonitrile in 50/50 volume ratio was studied. Synthesized polyaniline in powder shape is used as an adsorbent to remove toxic hexavalent chromium from aqueous solutions. Experiments were conducted in batch mode with different variables such as agitation time, solution pH and initial concentration of hexavalent chrom...

Chromium exists in sediments in two oxidation states: Cr(III), which is relatively insoluble and nontoxic, and Cr(VI), which is much more soluble and toxic. Chromium(VI) is thermodynamically unstable in anoxic sediments, and acid-volatile sulfide (AVS) is formed only in anoxic sediments; therefore sediments with measurable AVS concentrations should not contain toxic Cr(VI). If this hypothesis h...

The goal of this experiment was to investigating of effects of different levels of nano chromium (N-Cr) in diet on egg quality and blood chromium content of japanese quail. Two hundred and forty laying japanese quail (45 day old) were randomly distributed to 20 experimental unit with 12 birds in cage pens of 40 × 80 cm. Experimental treatments include: 1) control national research council (NRC,...

Chromium is a highly toxic non-essential metal for microorganisms and plants. Due to its widespread industrial use, chromium (Cr) has become a serious pollutant in diverse environmental settings. The hexavalent form of the metal, Cr(VI), is considered a more toxic species than the relatively innocuous and less mobile Cr(III) form. The presence of Cr in the environment has selected microbial and...

Aqueous plant leaves extract (PLE) of an abundant shrub, Sorbaria sorbifolia, was explored for the reduction of hexavalent chromium, Cr(VI), to trivalent chromium, Cr(III). The effect of contact time, pH, PLE quantity, ionic strength, hardness, temperature and effective initial Cr(VI) ion concentration were tested; Cr(VI) reduction followed the pseudo-first order rate kinetics and maximum reduc...

A relatively simple, sensitive, selective, automatic fluorimetric method for the simultaneous determination of chromium(III) and chromium(VI) by flow injection analysis (FIA) was developed. The method is based on the selective oxidation of the non-fluorescing reagent 2-(a-pyridyl)thioquinaldinamide (PTQA), which with Cr yields an intensely fluorescent product (lex = 360 nm; lem = 500 nm). Chrom...

rinking water utilities face the challenge of addressing emerging water quality concerns to ensure adequate protection of public health, sometimes without final federal or state drinking water regulations. Total chromium, i.e., trivalent chromium [Cr(III)] plus hexavalent chromium [Cr(VI)], has been regulated by national drinking water regulations since 1975. The federal regulatory maximum cont...

To investigate the correlations among seminal plasma Magnesium (Mg), Phosphorus (P), Potassium (K), Calcium (Ca), Chromium (Cr), Manganese (Mn), Iron (Fe), Copper (Cu), Zinc (Zn), Selenium (Se), Molybdenum (Mo) and Iodine (I) concentrations and semen parameters [1– 15]. 500 fertile and 1000 infertile males provided a standardized semen specimen. Total Magnesium (Mg), Phosphorus (P), Potassium (...