We consider exclusive π production in ep-scattering. At high energies odderon and photon exchange contribute. The photon exchange contribution is evaluated exactly using data for the total virtual photon-proton absorption cross section. The odderon exchange contribution is calculated in nonperturbative QCD, using functional integral techniques and the model of the stochastic vacuum. For the pro...

The early steps of the proposed mechanistic pathway for dehydroquinate synthase have been probed with a series of substrate analogues. These analogues, 3-9, are structurally prohibited from undergoing the beta-elimination of inorganic phosphate that represents the committed step in the conversion of the substrate 3-deoxy-D-arabino-heptulosonate 7-phosphate (1) to dehydroquinate (2). In agreemen...

Several laboratories have reported that the activities of sodium-lithium countertransport are increased in red blood cells from patients with essential hypertension. Based on the many similarities between this transport system and the renal sodium-proton exchanger, a hypothesis has been put forth in the literature that increased red blood cell sodium-lithium countertransport activity may be a m...

We have measured the pH dependence of the kinetics of C 0 2 hydration catalyzed by carbonic anhydrase I11 from the skeletal muscle of the cat. Two methods were used: an initial velocity study in which the change in absorbance of a pH indicator was measured in a stopped flow spectrophotometer, and an equilibrium study in which the rate of exchange of "0 between C 0 2 and H 2 0 was measured with ...

The chiral two-pion exchange component of the long-range pp interaction is studied in an energy-dependent partial-wave analysis. We demonstrate its presence and importance, and determine the chiral parameters ci (i = 1, 3, 4). The values agree well with those obtained from pion-nucleon amplitudes. 11.80.Et, 12.39.Fe, 13.75.Cs, 21.30.-x Typeset using REVTEX

Sulfonated sPPFS-b-PBuA diblock and statistical copolymers based on 2,3,4,5,6-pentafluorostyrene PFS butyl acrylate BuA were elaborated for Proton Exchange Membrane Water Electrolyser (PEMWE) purposes. The block (BCP) synthetized by Nitroxide Mediated Polymerization NMP, a controlled radical polymerization technique that yields well-defined molar mass low dispersity material. These diblock-copo...

The interaction of AMP and fructose 2,6-bisphosphate with rabbit liver fructose-1,6-bisphosphatase has been investigated by proton nuclear magnetic resonance spectroscopy (1H NMR). The temperature dependence of the line widths of the proton resonances of AMP as a function of fructose-1,6-bisphosphatase concentration indicates that the nucleotide C2 proton is in fast exchange on the NMR time sca...

Exchange of intracellular sodium for extracellular lithium readily occurs in vascular smooth muscle, but the mechanism of this exchange is not known. These studies examined whether a sodium-lithium countertransport system was present in the cell membrane of vascular smooth muscle. A sarcolemmal-enriched vesicle preparation was obtained from canine superior mesenteric artery via a magnesium aggr...

In this work, we have investigated a novel distal proton shuttle mechanism of ribosome catalyzed peptide bond formation reaction. The reaction was found to follow a two-step mechanism. A distal water molecule located about 6.1 Å away from the attacking amine plays as a proton acceptor and results in a charge-separated intermediate that is stabilized by the N terminus of L27 and the A-site A76 5...