Nanostructured ultrathin films of pendant carbazole-modified polyelectrolytes were fabricated using the layer-by-layer deposition technique in order to correlate the importance of highly ordered structures and well-defined layer composition in electrochemical cross-linking and nanopatterning. Both UV-vis and surface plasmon resonance (SPR) spectroscopy studies indicated differences in the film ...

The title compound, C(19)H(20)BrNO(2), consists of a carbazole skeleton with methyl groups at positions 1 and 4, a protecting group located at the N atom and a Br atom at position 6. The pyrrole ring is oriented at dihedral angles of 1.27 (7) and 4.86 (7)° with respect to the adjacent benzene rings. The dihedral angle between the benzene rings is 5.11 (7). The crystal structure is determined ma...

In the title compound, C(27)H(19)NO(2)S, the naphtho-carbazole unit is approximately planar (r.m.s. deviation = 0.002 Å) except for the N atom, which is displaced by 0.122 (1) Å out of the mean plane. The dihedral angle between the naphtho-carbazole mean plane and the phenyl ring of the phenyl-sulfonyl substituent is 83.16 (3)°. An inter-molecular C-H⋯π inter-action involving the phenyl group a...

The asymmetric unit of the title compound, C(26)H(28)BrN, contains two independent mol-ecules in which the carbazole rings are almost planar, with r.m.s. deviations of 0.0212 (1) and 0.0229 (1) Å. The dihedral angles between the carbazole ring system and the pendent benzene ring are 60.5 (1) and 56.3 (1)° in the two mol-ecules. In the crystal, mol-ecules are linked into chains along the b axis ...

In this study, immobilized CuAlO2 onto the ZSM-12&35 composite was prepared and used as a photocatalyst to remove N-containing oil pollutants (Carbazole) through advanced oxidation. In this method, acetone is used as a reaction solvent that can be partially converted to fuel oxygenates compounds (Octane enhancers) through an aldol condensation reaction. Photocatalyst characterization was perfor...

5,12-Dihydroindolo[3,2-a]carbazole is a polycyclic structure combining in its scaffold two carbazole moieties sharing fused aromatic ring. Since the pioneering works reported 2019 on this concerning substitution of carbazoles by similar functional groups, no recent investigation has been devoted to asymmetrize carbazoles. In work, series 13 compounds based 5,12-dihydroindolo[3,2-a]carbazole pre...

Carbazole dendrimers up to 4th generation were synthesized. They showed significantly high T(g), amorphous and stable electrochemical properties, and great potential as solution processed hole-transporting materials for OLEDs. Alq3-based green devices exhibited high luminance efficiency and CIE coordinates of 4.45 cd A(-1) and (0.29, 0.53), respectively.

Nanoparticles of a novel boron-based carbazole derivative have been reported. They exhibit efficient green fluorescence, aggregation induced ratiometric fluorescence change and green/blue fluorescent switching to sense VOCs.

We report the first total synthesis of oxydimurrayafoline via nucleophilic substitution at the benzylic position at C-3 of the carbazole framework.

Acriflavine treatment on Streptomyces tendae generated a bald mutant (bld-1) with an altered antibiotic pattern. The parental strain produced nikkomycins and juglomycins, whereas the mutant bld-1 was only capable of juglomycin synthesis. The existence of a mutant defective in morphogenesis and in nikkomycin biosynthesis suggests a common regulation of these processes. An interesting finding of ...