The reactions of 2,2'-dimethoxy-1,1'-binaphthyl-3,3'-bis(4-vinylpyridine)(L) with AgNO3 or AgClO4 at 70 degrees C gave rise to two novel luminescent homochiral lamellar coordination polymers, AgL2X (X = NO3- for 1 or ClO4- for 2), which are built from linking helical chains by Ag(I) atoms as hinges.

This paper describes step-economic iodine-mediated construction of functionalized arylazopyrazoles in the presence of catalytic AgNO3 starting from simple β-ketoesters and two equivalents of arylhydrazines. This cascade reaction includes in situα-iodination of β-ketoesters, pyrazol-3-one formation, substitution with a nitrogen nucleophile, and oxidation/aromatization.

Unprecedented domino oxidative cyclization reactions of unprotected 2-alkynylanilines to give functionalized 4H-benzo[d][1,3]oxazin-4-one or benzisoxazole derivatives in moderate to good yields are achieved by silver vs. gold selective catalysis. The search for the optimal reaction conditions revealed the divergent catalytic activity of NaAuCl4·H2O and AgNO3.

Abbreviations: ACC: 1-Amino-cyclopropane-1-carboxylic acid ADC: arginine decarboxylase AgNO3: silver nitrate AVG: aminoethoxyvinylglycine BA: 6-benzylaminopurine DFMA: α-DL-difluromethyl arginine DFMO: α-DL-difluromethyl ornithine IAA: indole acetic acid NAA: α-naphthalene acetic acid ODC: ornithine decarboxylase PA: polyamine Put: putrescine SAM: S-adenosyl-Lmethionine STS: silver thiosulphate...

A self-assembled poly(amide-triazole) physical gel (1) was found to show responsive behaviour towards halide anions, while the corresponding monomeric (2) and dimeric homologues (3) were non-gelating. In the presence of halide anions, polymer gel 1 collapsed to become a solution, but could be restored back to the gel state after addition of a AgNO3 salt.

Chitosan was modified by substituting alkynyl silver on chitosan (Ag-CS) through a two-step chemical modification to form novel antimicrobial coating material. The physicochemical property, activity, cytotoxicity, and potential food applications of Ag-CS were systematically investigated. presented smooth sheet structure, demonstrated stronger effects than either acetate (AgOAc) or nitrate (AgNO...

BACKGROUND It was the aim of this study to evaluate the antibacterial impact of two silver(I) carbohydrate complexes with tripodal thioglycosides, namely tris[2-(β-D-thio-glucopyranosyl)ethyl]-amine-silver(I)-nitrate (3) and tris[2-(α-D-thio-manno-pyranosyl)ethyl]-amine-silver(I)-nitrate (4), on five oral pathogenic bacterial strains. Furthermore, cytocompatibility was tested using human gingiv...

To establish an efficient plant regeneration system of Cassia mimosoides, the 10-day-old seedlings were used as explants for inducing lateral buds. Results showed that addition BA and NAA different ratios on basis 1/2 MS could effectively induce production By adding additional elements, it was found growth buds longer stronger medium + 3.0 mg/l 0.1 4.0 Gln or 1.0 AgNO3. Meanwhile, cutting with ...

Binary metallic alloy nanomaterials (NMs) have received significant attention because of their widespread application in photoelectrocatalysis, electronics, and engineering. Although various synthetic methods been adopted to prepare binary NMs, the formation bimetallic NMs by irradiating mixed solutions metal salts powders, using a nanosecond pulsed laser absence any reducing agent, is rarely r...