Abstract Alkyl bromides are used as initiators in most of the atom transfer radical polymerization (ATRP) process and play an important role for controlling ATRP equilibrium. In this work, effect solvent on equilibrium constant ( K ) rate activation k act three isomeric alkyl [namely, N -phenyl(3-bromo-3-methyl)succinimide, -phenyl(3-bromo-4-methyl)succinimide, -phenyl(3-bromomethyl)succinimide...
