نتایج جستجو برای: brönsted acid
تعداد نتایج: 747496 فیلتر نتایج به سال:
A simple and mild method for tetrahydropyranylation of alcohols is reported at room temperature using a catalytic amount of 3-methylimidazolinium hydrogensulfate([Hmim]HSO4) as a green, efficient and reusable catalyst. Using solvent-free conditions, non-toxic and inexpensive materials, modest and clean work-up, short reaction times and high yields of the products are the advantages o...
در سال های اخیر،کاربرد نانوکاتالیست های ناهمگن بر پایه ی پالادیوم به طور وسیعی گسترش یافته است. در این پایان نامه، ابتدا کمپلکس های تک هسته ای پالادیوم به دو صورت پالاداسیکل و مسطح مربعی با استفاده از لیگاندهای 4- برموبنزوکسیم، 2و4و6- تری متیل پیریدین و پیریدین به ترتیب زیر سنتز شدند. [pd(oac){c,n-(c6h3brc(ch)=noh)-2}(py)] (1) [me3pyh][pd(me3py)(cl)3] (2) جهت شناسایی کمپلکس های سنتز...
Buffer catalysis and solvent kinetic isotope effects in the cyclization of methyl-substituted ethyl hydantoates with ωN-methyl (MUE) and ω-N-phenyl groups (PUE) have been studied in an attempt to elucidate the changes in mechanism and eventual reversal of relative reactivities caused by increasing the number of substituent methyl groups (the gem-dimethyl effect). (Rate constants for the hydroxi...
The principal objective of this lecture is to describe the efficacy of organometals as electron donors, and to show how this property dominates many aspects of their chemistry. First, the structural effects of alkyl ligands (B) on the highest occupied molecular orbital (HOMO) of the neutral alkylmetals, R4Sn, R4Pb and R2Hg, are probed by photoelectron spectroscopy. The chemical properties of th...
از روش استخراج با سیال فوق بحرانی (sfe) برای استخراج روغن های دانه بادام استفاده گردیده است. پارامتر های آزمایشی موثر در روش sfe مثل فشار، دما، حجم اصلاحگر، زمان استخراج استاتیک و دینامیک با استفاده از یک طراحی مختلط مرکزی(ccd) بعد ازطراح فاکتوریال جزئی 2n–1بهینه شدند.جهت بهینه سازی شرایط استخراج از طراحی مرکب مرکزی (ccd) پس از یک مرحله غربال گری استفاده شد. مدل استفاده شده، شرایط استخراج شامل ...
a simple, sensitive and selective method for solvent extraction and spectrophotemetric determination of lanthanum (ii) europium (iii), and cerium (iii) is described , the rare earth metals are extracted into chloroform solution of n-phenylbenzohydroxamic acid (pbha) at ph 9-10 various parameters are studied to optimize the extraction conditions. the molar absorptivity is found to increase from ...
background and objectives: betulinic acid (ba), oleanolic acid (oa) and ursolic acid (ua) are well-known pentacyclic triterpenoids (pts), which are produced by plants. they possess a variety of beneficial effects including anti-inflammatory, hepatoprotective, antitumor, anti-hiv, antimicrobial, gastroprotective, and antihyperlipidemic activities. in the present study, quantitative determination...
Silent information regulator 2 (Sir2) enzymes catalyze NAD+-dependent protein/histone deacetylation, where the acetyl group from the lysine epsilon-amino group is transferred to the ADP-ribose moiety of NAD+, producing nicotinamide and the novel metabolite O-acetyl-ADP-ribose. Sir2 proteins have been shown to regulate gene silencing, metabolic enzymes, and life span. Recently, nicotinamide has ...
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