Quaternized polymers as ionomeric binders in the electrode enable operation of alternative fuel cells under high pH conditions or anhydrous to overcome challenges proton exchange membrane cells. Hydrophobicity ionomers derived from fluorine content is beneficial performance, but due synthetic difficulties, not many fluorinated quaternized have been reported with their influence on behavior thes...

A major, unprecedented improvement in the durability of polymer electrolyte membrane fuel cells is obtained by tuning the properties of the interface between the catalyst and the ionomer by choosing the appropriate dispersing medium. While a fuel cell cathode prepared from aqueous dispersion showed 90 mV loss at 0.8 A cm(-2) after 30,000 potential cycles (0.6-1.0 V), a fuel cell cathode prepare...

Cytotoxicity testing of dental restorative materials must be viewed as an assessment of hazards, that is the potential of the material to cause pulpal problems. In this context, composites, glass ionomers, amalgams, zinc-based cements and peroxide bleaching agents are all possible hazards to the pulp. The risks that these materials will cause pulpal toxicity in vivo can be partly estimated by a...

Glass ionomer cement systems have become important dental restorative and luting materials for use in preschoolers, children and teenagers. These materials form chemical bonds to tooth structure, are biocompatible, release fluoride ions for uptake by enamel and dentin, and are able to take up fluoride ions from dentifrices, mouthwashes, and topically applied solutions. Unlike early glass ionome...

We have found that not only block copolymers but also ionomers can self-assemble in a selective solvent to form surfactant-free nanoparticles. The self-assembly can be induced by chemical reaction, polymer-polymer complexation, and microphase inversion in addition to the temperature. A recently developed microwave method for the preparation of uniform surfactant-free polymeric nanoparticles is ...