Abstract New N2O2 type Schiff base has been designed and synthesized by condensing 2,4 dihydroxy benzaldehyde and α-naphthylamine in ethanol. Solid metal complexes of the schiff base with Cu(II), Ni(II) and Zn(II) metal ion were synthesized and characterized by elemental analysis, magnetic susceptibility, molar conductance, IR, UV-Vis and ‘H NMR spectral studies. The data shows that the c...

Metal chelates, [M(HL)2(H2O)2]X2 (where M= Mn(II), Co(II), Cu(II), Ni(II) or Zn(II), X= NO3–or Cl– and HL= Schiff base moiety), have been prepared and characterized by elemental analysis, magnetic and spectroscopic measurements (infrared, X-ray powder diffraction and scanning electron microscopy). Elemental analysis of the metal complexes was suggested that the stoichiometry is 1:2 (metal-ligan...

Background: The purpose of this study was to compare and evaluate the effects of metal primer on the shear bond strength of denture base resin to base metal alloy after electrolytic and laser etching. Materials and Methods: A total of 48 cobalt‐chromium (Co‐Cr) alloy specimens were fabricated. The specimens were divided into 6 groups of 8 specimens each. Group I: Sandblasting (control group). G...

A new Schiff base has been synthesized from 3-(3-nitrophenyl)-1-phenyl-1H-pyrazole-4carbaldehyde and O-amino phenol. Metal complexes of the Schiff base have been synthesized from acetate salt of Cu (II), Co (II) and Ni (II) metal in the alcoholic medium. The newly prepared Schiff base ligand and metal complexes have been characterized by various physicochemical techniques such as Elemental anal...

Dehydroformylation, or the reaction of aldehydes to produce alkenes, hydrogen gas, and carbon monoxide, is a powerful transformation that is underdeveloped despite the high industrial importance of the reverse reaction, hydroformylation. Interestingly, nature routinely performs a related transformation, oxidative dehydroformylation, in the biosynthesis of cholesterol and related sterols under m...

recently, the use of renewable energies has increased to  environmental pollution, limitation of fossil energy resources and energy security  one of the means that enable us to use such energies is fuel cells (fc). however, there are many problems  in the commercialization of fc from an economically and operation perspective. one of the most important problems is heat management. new heat pipes...