In this paper the results of both modeling and testing a representative 3-ton air-to-air heat pump running with the baseline refrigerant (HCFC-22) and zero ODP alternative refrigerants will be presented. Alternative refrigerant simulation runs are made with two pure fluids (HFC-134a and HFC-152a) and an azeotropicmixture (60/40wt%) ofHFC-32 and HFC125 (Allied-Signal Inc. U.S. Patent 4,978,467)....

Asymmetric transfer hydrogenation (ATH) has been widely used as an efficient and practical method for preparation of optically pure secondary alcohols that are important key intermediates for the synthesis of a large number of pharmaceutical substances. One of the most attractive catalyst system is based on Ru-TsDPEN (TsDPEN= N-(p-tolylsulfonyl)-1,2diphenylethylenediamine) complexes, which was ...

Sugar fatty acid esters (SFAE) are well known as bio-surfactants. Their excellent biodegradability as well as the fact that they are tasteless, odorless, nontoxic, non-irritant and non-ionic explains their increasing importance in numerous areas. On the other hand, for a long time, large scale production of SFAE remained mainly in the realms of organic chemistry and chemical processing. Chemica...

This study examined the extent of organic solvent and water retention in comonomer blends with different hydrophilicity (Hoy’s solubility parameter for hydrogen bonding, δh) after solvent evaporation, and the extent of tracer penetration in polymerised films prepared from these resins. For each comonomer blend, adhesive/solvent mixtures were prepared by addition of [1] 50wt% acetone; [2] 50wt% ...

This study examined the extent of organic solvent and water retention in comonomer blends with different hydrophilicity (Hoy’s solubility parameter for hydrogen bonding, δh) after solvent evaporation, and the extent of tracer penetration in polymerised films prepared from these resins. For each comonomer blend, adhesive/solvent mixtures were prepared by addition of [1] 50wt% acetone; [2] 50wt% ...

Nucleophilic trapping of iminium salts generated via oxidative functionalisation of tertiary amines is well established with stabilised carbon nucleophiles. The few reports of organometallic additions have limited scope of substrate and organometallic nucleophile. We report a novel, one-pot methodology that functionalises N-substituted tetrahydroisoquinolines by visible lightassisted photooxida...

Nucleophilic trapping of iminium salts generated via oxidative functionalisation of tertiary amines is well established with stabilised carbon nucleophiles. The few reports of organometallic additions have limited scope of substrate and organometallic nucleophile. We report a novel, one-pot methodology that functionalises N-substituted tetrahydroisoquinolines by visible lightassisted photooxida...