The corrosion behaviour of aluminium and6063 aluminium alloy was investigated in phosphoric acid of different concentrations at different temperatures. The study was done by electrochemical method, using Tafel polarization and electrochemical impedance spectroscopy (EIS) techniques. The kinetic parameters and thermodynamic parameters were calculated using Arrhenius theory and transition state t...

We present a shear-transformation-zone (STZ)-based analysis of numerical simulations by Haxton and Liu [Phys. Rev. Lett. 99, 195701 (2007)]. The extensive Haxton and Liu (HL) data sharply test the basic assumptions of the STZ theory, especially the central role played by the effective disorder temperature as a dynamical state variable. We find that the theory survives these tests, and that the ...

Fully resolved predictions of steady, one-dimensional detonations near the ChapmanJouguet state in mixtures of methane-air and methane-oxygen-argon are presented. The model is restricted to inviscid continuum mixtures of calorically imperfect ideal gases described by detailed Arrhenius kinetics. Consistent with estimates from an underlying molecular collision theory, an eigenvalue analysis of l...

Molecular dynamics simulations have been used extensively to model the folding and unfolding of proteins. The rates of folding and unfolding should follow the Arrhenius equation over a limited range of temperatures. This study shows that molecular dynamic simulations of the unfolding of crambin between 500K and 560K do follow the Arrhenius equation. They also show that while there is a large am...

We introduce a coarse-grained model for atomic glass formers. Its elements are physically motivated local microscopic dynamical rules parameterized by observables. Results of the model are established and used to interpret the measured behaviors of supercooled fluids approaching glass transitions. The model predicts the presence of a crossover from hierarchical super-Arrhenius dynamics at short...

Rose and Caron (2007) have compiled a comprehensive data set of individual growth rates of planktonic protists in an attempt to answer a fundamental question in marine ecology: ‘‘Why are blooms of phytoplankton such common events in the ocean?’’. They reach the interesting conclusion that, because the temperature dependence of the growth rate of heterotrophic protists is much stronger than that...

1. The effect of temperature on the reaction time of Mya to light is mainly confined to the latent period. The sensitization period, representing a photochemical process, is changed comparatively little. 2. The relation between the latent period and the temperature is adequately expressed by the Arrhenius equation, for temperatures below 21 degrees C. Above this temperature, the latent period b...

A nonlinear mathematical model was developed and experimentally validated to investigate the effects of changes in optical properties during interstitial laser photocoagulation (ILP). The effects of dynamic optical properties were calculated using the Arrhenius damage model, resulting in a nonlinear optothermal response. This response was experimentally validated by measuring the temperature ri...

Abstraction of hydrogen atoms by pthalimide-N-oxyl radicals is an important step in the N-hydroxyphthalimide catalyzed autoxidation of hydrocarbons. In this contribution, the temperature dependency of this reaction is evaluated by a detailed transition state theory based kinetic analysis for the case of toluene. Tunneling was found to play a very important role, enhancing the rate constant by a...

Incineration of municipal solid waste (MSW) is one of the key scopes in the global clean energy strategy. A computational fluid dynamics (CFD) model was established in order to reveal these features of the combustion process in a fixed porous bed of MSW. Transporting equations and process rate equations of the waste bed were modeled and set up to describe the incineration process, according to ...