poly(p-n-chlorostyrenesulphonamide) synthesized via direct chlorination of poly[(p-styrene) sulphonamide], can be used for selective chlorination of aromatic compounds. aromatic rings of the anisole, p-xylene, ethylbenzene and toluene are chlorinated with good yields. the polymer can be recovery, rechlorinated and reused several times.

Aromatic residues are key widespread elements of protein structures and have been shown to be important for structure stability, folding, protein-protein recognition, and ligand binding. The interactions of pairs of aromatic residues (aromatic dimers) have been extensively studied in protein structures. Isolated aromatic molecules tend to form higher order clusters, like trimers, tetramers, and...

reactions of n-isocyaniminotriphenylphosphorane with cyclopentanone have been studied in the presence of aromatic carboxylic acids and primary amines, proceeds smoothly at room temperature under neutral conditions to afford sterically congested 1,3,4-oxadiazole derivatives by an intramolecular aza-wittig cyclization in ch2cl2 in excellent yields. the structures of the products were deduced from...

a sequential process strategy was introduced for the synthesis of 2,3,4,5-tetrasubstituted pyrroles by the formation of benzoin from the corresponding aromatic aldehyde and followed by condensation reaction with 1,3-dicarbonyl compounds and ammonium acetate in the presence of diethylene glycol-bis(3-methylimidazolium) dihydroxide as catalyst in refluxing ethanol. the recycled catalyst could be ...

polycyclic aromatic hydrocarbons (pahs) in the priority controlling list of us epa weresystematically evaluated in surface sediments in dianchi lake and its estuaries. total pah concentrations(σpahs) varied from 210 to 11,070 ng/g dry weight (d.w.) in dianchi lake, and from 230 to 12,271 ng/g d.w.in the estuaries. σpahs in sediments from caohai section were higher than those from waihai section...

Geometries of aromatic/aromatic interactions in crystal structures small molecules from the Cambridge Structural Database (CSD) (benzene/benzene, toluene/toluene, and p-phenol/p-phenol interactions) protein Protein Data Bank (PDB) (Phe/Phe Tyr/Tyr were studied compared. The data show a larger influence packing/surrounding, more than substituents, on geometries interactions. While CSD preference...

background and objectives: the effect of the different proteins and polysaccharides on the characteristics of low-fat cheese has been a topic of recent study. the release of aromatic compounds from the cheese is affected by the addition of texture improvers. the present study investigated the addition of polysaccharides and proteins on the hardness, microstructure and ester release of low-fat b...