Earlier, we reported the formation of unidentified strong irritants in reaction mixtures of terpenes and ozone. The identified products included aldehydes, ketones and carboxylic acids. Here we report the effects of relative humidity and reaction time on irritant formation in our flow reaction system using limonene and isoprene. Upper airway irritation was measured in mice (via reduction of res...

An observational based analysis of ozone production for Raleigh and Charlotte, North Carolina, was performed for the years 1981±1990. A trend analysis was carried out for the 10 yr period for Raleigh. The third quartile average for Raleigh indicated a slight upward trend of about 0.5 parts per billion by volume (ppbv) per year in ozone concentration, but this may not be statistically signi®cant...

Fine particulate matter air pollution plus ozone impairs vascular function and raises diastolic blood pressure. We aimed to determine the mechanism and air pollutant responsible. The effects of pollution on heart rate variability, blood pressure, biomarkers, and brachial flow-mediated dilatation were determined in 2 randomized, double-blind, crossover studies. In Ann Arbor, 50 subjects were exp...

During the early morning hours on April 29, 2000, a time series of ozone observations from several stations showed that a unique and exceptional ozone episode occurred in Madrid city and surrounding areas, whereby monitoring stations reported ozone concentrations up to 1190 mg/m. In order to investigate this phenomenon, two different air quality modeling approaches are used here: U The FLEXTRA ...

Air pollution forecasts in major urban areas are becoming a problem concerning the day to day environmental management for city authorities. This paper describes the development of an application to forecast the peak ozone levels with the aid of meteorological and air quality variables, in the Greater Athens Area. For this purpose, a number of regression models were considered, while the select...

Not much has been written about air cleaning from ozone. The aim of this paper was to demonstrate the possibility of adsorption air cleaning from ozone. The second aim was to investigate the dependence of the efficiency of ozone removal from the air on the height of the adsorber layer and on concentrations of ozone, and to obtain empirical formulas for calculating the efficiency of ozone treatm...

Ground-level ozone (O(3)) and fine particulate matter (PM(2.5)) are associated with increased risk of mortality. We quantify the burden of modeled 2005 concentrations of O(3) and PM(2.5) on health in the United States. We use the photochemical Community Multiscale Air Quality (CMAQ) model in conjunction with ambient monitored data to create fused surfaces of summer season average 8-hour ozone a...

Hydrocarbon Processing Industries (HPIs) emit large amounts of highly reactive hydrocarbons and Nitrogen Oxides to the atmosphere. Such simultaneous emissions of ozone precursors result in rapid and high yields ozone (O3) formation downwind. The climate of the Middle East has been shown to be favorable for O3 formation in summer. There are also vast activities in processing oil and gas in this ...

Experiments were conducted to identify the emissions from the car air freshener and to identify the formation of ultra-fine particles and secondary gaseous compounds during the ozone-initiated oxidations with emitted volatile organic compounds (VOCs). The identified primary constituents emitted from the car air freshener in this study were alpha-pinene, beta-pinene, p-cymene, and limonene. Form...

Ground-level tropospheric ozone is one of the air pollutants of most concern. It is mainly produced by photochemical processes involving nitrogen oxides and volatile organic compounds in the lower parts of the atmosphere. Ozone levels become particularly high in regions close to high ozone precursor emissions and during summer, when stagnant meteorological conditions with high insolation and hi...