نتایج جستجو برای: actinide
تعداد نتایج: 1114 فیلتر نتایج به سال:
The ketimide anion R2C=N(-) is an important class of chemically robust ligand that binds strongly to metal ions and is considered ideal for supporting reactive metal fragments due to its inert spectator nature; this contrasts with R2N(-) amides that exhibit a wide range of reactivities. Here, we report the synthesis and characterization of a rare example of an actinide ketimide complex [Th(BIPM...
The first actinide triple helices, including two supramolecular conformational isomers of uranium(VI), have been synthesized with the aid of a flexible V-shaped ligand and a rigid aromatic base. The isomers exhibit an intriguing pH-dependent structural evolution and a kinetically-controlled transformation via a novel conformational rearrangement of the organic base.
— On the basis of systematic trends in X-ray photoemission core-level spectra of the rare earth elements and the adjacent elements, it is suggested that the 5s, 5p3/2 and 4d levels of the actinides should exhibit strong many-electron effects. The available actinide data appears to support the above predictions.
We show that plane wave ultrasoft pseudopotential methods readily extend to the calculation of the structural properties of lanthanide and actinide containing compounds. This is demonstrated through a series of calculations performed on UO, UO2, UO3, U3O8, UC2, alpha-CeC2, CeB6, CeSe, CeO2, NdB6, TmOI, LaBi, LaTiO3, YbO, and elemental Lu.
Covariance matrix evaluations in the fast energy range were performed for a large number of actinides, either using low-fidelity techniques or more sophisticated methods that rely on both experimental data as well as model calculations. The latter covariance evaluations included in the ENDF/B-VII.1 library are discussed for each actinide separately.
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