Standard thermodynamic function changes (AGO”, AHe’, A&” and Acre”) are reported for proton dissociation of acridinium cation in aqueous solution. These values have been determined from a series of precise and accurate acid equilibrium constants, K,. The equilibrium constants have been obtained spectrophotometrically over a range of temperatures from 2 to 66°C at several ionic strengths (I = 0....

Photostability is an essential design aspect for the overall performance of photocatalysts, particularly as groups introduced to adjust redox properties often constitute sites potential reactivity. Herein, we describe a modular and flexible synthetic approach incorporate diarylamino moieties with increased photostability that allow efficiently tune behavior new generation organic acridinium pho...

The genome of hepatitis C virus (HCV) consists of seven functional regions: the core, E1, E2/NS1, NS2, NS3, NS4, and NS5 regions. The U. S. Food and Drug Administration-licensed 2.0G immunoassay for the detection of anti-HCV uses proteins from the core, NS3, and NS4 regions (McHutchinson et al., Hepatology 15:19-25, 1992). The 3.0G enzyme-linked immunosorbent assay includes the protein from the...

BACKGROUND Detection of telomere repeats by Southern hybridization of genomic DNA is time consuming, and the reading of a mean terminal restriction fragment (TRF) length from a smear pattern of an autoradiogram can be inaccurate. We developed a hybridization protection assay (HPA) for telomere repeats. METHODS We heated 5 microL of DNA solution or 10 microL of cell or tissue lysate at 95 degr...

A chemiluminescent DNA probe (Accuprobe) assay developed by Gen Probe, Inc., for the rapid identification of Histoplasma capsulatum was evaluated and compared with the exoantigen test by using 162 coded cultures including Histoplasma capsulatum var. capsulatum, Histoplasma capsulatum var. duboisii, Histoplasma capsulatum var. farciminosum, Blastomyces dermatitidis, Coccidioides immitis, Paracoc...

the aim of this work is to probe the influence of nanoclay and turmeric spends content on microcrystalline of vinyl ester hybrid nanocomposites. a series of vinyl ester hybrid nanocomposites have been fabricated with varying amounts of ts viz., 0, 2.5, 5, 7.5 and 10 % w/w along with 2% nanoclay. the microcrystalline parameters such as crystallite size and lattice strain of vinyl ester hybrid na...

The aim of this work is to probe the influence of nanoclay and turmeric spends content on microcrystalline of vinyl ester hybrid nanocomposites. A series of vinyl ester hybrid nanocomposites have been fabricated with varying amounts of TS viz., 0, 2.5, 5, 7.5 and 10 % w/w along with 2% nanoclay. The microcrystalline parameters such as crystallite size and lattice strain of vinyl ester hybrid na...

Iridium- and ruthenium-free approaches to protected allylic amines and alkyl nitriles under photoredox conditions are reported. An inexpensive organic dye, eosin Y, catalyzes coupling of Boc-protected potassium α-aminomethyltrifluoroborates with a variety of substituted alkenyl sulfones through an α-aminomethyl radical addition-elimination pathway. Allylic and homoallylic amines were formed in ...

Abstract A dehydrogenative functionalization of styryl carbon‐carbon double bonds with triflamide is described via dual visible‐light photoredox/cobaloxime catalysis. range allylic triflamides (20 examples) were isolated in moderate to good yields (up 88%) under stoichiometric acceptorless conditions. Dedicated labelling, as well spectroscopic experiments, enabled shed light on the concatenated...