A method for acetylene inhibition measurements of denitrification in the field using micrometeorological techniques is presented. It is based on the monitoring of flux ratios from small (<5 m2) microplots. The method measures concentration profiles close to the surface, and from these the ratio of gradients, which can be assumed to be equal to the ratio of fluxes, is calculated. Acetylene has b...

The dipotassium salts of maleic, fumaric and acetylenedicarboxylic acids were electrooxidized and the reaction products were analyzed qualitatively and quantitatively by UV/VIS and FT-IR spectroscopy. Acetylene, carbon dioxide and carbon monoxide, along with polyynes, are the products obtained from maleic and fumaric acids. The best acetylene yields are obtained from fumaric acid and not from m...

By acetylene pyrolysis at 650 and 5508C, carbon nanotubes were synthesized successfully in porous alumina templates anodized in sulfuric and/or oxalic acid solution. For templates anodized in oxalic acid followed by boiling in distilled water, thermal decomposition of acetylene at 6508C in the pores results in the formation of carbon nanofibres. For templates anodized in sulfuric acid, only car...

A method has been developed for culturing detached nitrogen-fixing root nodules of lupin (Lupinus angustifolius L.) on a simple nutrient medium. Under the best conditions devised, the acetylene reduction activity of mature detached nodules was maintained at 10 to 25 nmoles of ethylene hr(-1) mg(-1) fresh weight for 3 days. Under the same culture conditions, immature nodules increased their acet...

The growth of a filamentous fungus, a Graphium sp., on n-alkanes (C(inf2) to C(inf4)) was inhibited by low concentrations of acetylene, propyne, 1-butyne, ethylene, and propylene. Acetylene and other unsaturated hydrocarbons had no effect on the growth of the Graphium sp. on potato dextrose broth, ethanol, or acetate. Our results suggest that n-alkynes and n-alkenes are selective inhibitors of ...

Lake water samples were observed to transform [14-C]ethylene into water-soluble compounds that were undetectable by conventional acetylene reduction assay procedures. Methane oxidizing bacteria, which are known to be common in freshwaters, appeared to be responsible for this activity. As much as 28 percent of added ethylene has been observed to be transformed and this figure is probably an unde...

The ambient air is entrained intensively into atmospheric pressure thermal plasma jets. A system for shielding plasma jet has been used to improve jet characteristics and reduce oxygen content. Different gases have been applied as a shroud gas – argon, acetylene, methane, mixtures of acetylene-nitrogen and hydrogen-nitrogen. All shroud gases used in experiments affected plasma jet making the pr...

The capacity for dissimilatory reduction of NO(3) to N(2) (N(2)O) and NH(4) was measured in NO(3)-amended marine sediment. Incubation with acetylene (7 x 10 atmospheres [normal]) caused accumulation of N(2)O in the sediment. The rate of N(2)O production equaled the rate of N(2) production in samples without acetylene. Complete inhibition of the reduction of N(2)O to N(2) suggests that the "acet...

The modeling, simulation, and dynamic optimization of an industrial reaction system for acetylene hydrogenation are discussed in the present work. The process consists of three adiabatic fixed-bed reactors, in series, with interstage cooling. These reactors are located after the compression and the caustic scrubbing sections of an ethylene plant, characterizing a front-end system; in contrast t...