In the title compound, [Cu(C(8)H(5)Cl(2)N(3)OS)(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by an O, an S and an N atom from the tridentate ligand 3,5-dichloro-salicylaldehyde thio-semi-carb-azonate ligand and one O atom from dimethyl-formamide. At the same time, the Cu atom is in contact with S and Cl atoms from another two complexes [...

In the mol-ecule of the title compound, C(13)H(8)Cl(3)N, the 4-chloro-aniline and 2,4-dichloro-benzaldehyde moieties are planar with r.m.s. deviation of 0.0115 and 0.0116 Å, respectively, and are oriented at a dihedral angle of 13.94 (8)°.

Direct glycosylation of the sodium salt of 4,6-dichloro- or 4,6-dibromo-2-methylthiopyrrolo[2,3-d]pyrimidine with 2,3,5-tri-O-benzoyl-D-ribofuranosyl bromide gave good yield of the corresponding N7-glycosylated pyrrolo [2,3-d]pyrimidine. The intermediate 4-amino-6-chloro-2-methylthio-7-beta-D-ribofuranosylpyrrolo[2,3-d] pyrimidine provided a new synthetic route to tubercidin, via 6-chlorotuberc...

— — — — — — — — — — 3:36A 3:42A 3:58A 4:08A — 3:53A 3:55A 3:57A 3:59A 4:02A 4:05A 4:07A 4:09A 4:11A 4:13 4:16 4:21 4:25 — 4:21 4:23 4:25 4:27 4:30 4:33 4:35 4:37 4:39 4:41 4:44 4:49 4:53 4:31A 4:33 4:35 4:37 4:39 4:42 4:45 4:47 4:49 4:51 5:00 5:03 5:08 5:12 4:50 4:52 4:54 4:56 4:58 5:01 5:04 5:06 5:08 5:10 5:12 5:15 5:20 5:24 5:03 5:05 5:07 5:09 5:11 5:14 5:17 5:19 5:21 5:23 5:25 5:28 5:33 5:37...

The reaction of the neutral diphosphanide [(Im)P–P(Cl)(Dipp)] (6) (Im = 4,5-dichloro-1,3-bis(Dipp)-imidazol-2-yl; Dipp = 2,6-di-iso-propylphenyl) with methyl triflate (MeOTf) leads to the formation of cationic diphosphane [(Im)(Me)P–P(Cl)(Dipp)] (8) in a stereoselective methylation. In contrast, reacting 6 with the Lewis acid GaCl3 yields cationic diphosphene [( Im)PQP(Dipp)] (7), which is expl...

In the title mol-ecule, C(24)H(19)Cl(2)N(3), the dihedral angles between the benzotriazole group and the ethyl- and dichloro-substituted benzene rings are 16.53 (1) and 82.09 (1)°, respectively. The crystal structure is stabilized by weak inter-molecular C-H⋯O inter-actions.

In the structure of the 1:1 proton-transfer compound of 4-methyl-pyridine (γ-picoline) with 4,5-dichloro-phthalic acid, C(6)H(8)N(+)·C(8)H(3)Cl(2)O(4) (-)·H(2)O, determined at 200 K, the 4,5-dichloro-phthalate anions are bridged by the water mol-ecule through O-H⋯O(carbox-yl) hydrogen bonds, giving zigzag chains which extend along the c-axis direction. The 4-methyl-pyridinium cations are linked...

The conformation of the N-H bond in the structure of the title compound (3CPA), C(8)H(8)ClNO, is anti to the meta-chloro substituent, in contrast to the syn conformation observed for the ortho-chloro substituent in N-(2-chloro-phen-yl)acetamide, syn to both the ortho and meta chloro substituents in N-(2,3-dichloro-phen-yl)acetamide, and syn to the ortho chloro substituent in N-(2,4-dichloro-phe...