Concentrations of heavy metals (As, Co, Cu, Ni, Mo, Pb and Zn) are studied in the soil of Shiraz industrial complex zone, south Shiraz, Iran to asses metal contamination due to industrialization, urbanization and agricultural activity. Soil samples were collected from three different depths. The A and C depths are enriched with metals such as Ni, As, Mo, Cu, Pb and Zn, compared with the B depth...

concentrations of six heavy metals including cr, mn, ni, pb, v and zn were determined in topsoil (from 47 grid cells), surface water (4 streams) and groundwater (8 wells and 4 qanats) from an agriculturalarea located at south part of the iranian capital, near the tehran oil refinery. concentrations of the elementswere measured using flame and flameless atomic absorption spectrometry. based on t...

Glyoxalase pathway plays an important role in stress adaptation and many clinical disorders. The first enzyme of this pathway, glyoxalase I (GlxI), uses methylglyoxal as a substrate and requires either Ni(II)/Co(II) or Zn(II) for activity. Here we have investigated the origin of different metal ion specificities of GlxI and subsequent pattern of inheritance during evolution. Our results suggest...

Anion exchange reactions of a number of layered double hydroxides with inorganic anions were investigated. The five LDH systems used in this study were Mg-Al, Ni-Al, Co-Al, Zn-Al and Zn-Cr. Ni-Zn hydroxynitrate and Ni-Zn hydroxyacetate were the LHSs used in this work. In general, all the LDHs and nickel zinc hydroxysalts exhibited higher extent of exchange towards chloride ions. The extent of e...

Local structures around metal atoms in Hi and Zn substituted 132-hydroxy-bacteriochlorophyll a (Ni-HOB, and Zn-HOB) with and without insertion into the accessory bacteriochlorophyll a (BChla) sites in Rhodobacter sphaeroides photosynthetic reaction centers (RC) are studied using X-ray absorption spectroscopy. The penta-coordination of Ni-HOB and Zn-HOB in the RC is similar to that of BChl a in ...

In the present investigation flocculation of dissolved Cu, Zn, Pb, Ni and Mn in a series of mixtures with salinities ranging from 1.5 to 9.5% during mixing of Talar river water with the Caspian Sea water was studied. The flocculation trend of Zn (87.22%) >Mn (45.31%) >Pb (39.09%) >Cu (36.58%)>Ni (12.70%) indicates that Cu, Zn, Pb and Mn have non-conservative behavior and Ni has relatively conse...

17O NMR is used to probe the local influence of nonmagnetic Zn and magnetic Ni impurities in the superconducting state of optimally doped high TC YBa2Cu3O7. Zn and Ni induce a staggered paramagnetic polarization, similar to that evidenced above TC, with a typical extension xi=3 cell units for Zn and xi>or=3 for Ni. In addition, Zn is observed to induce a local density of states near the Fermi e...

The focus of the review is on the specific aspects of Ni and Zn effects on growth morphology, Biochemical activity/responses, mineral nutrition and enzyme activity of plants. The quantity of Ni required for normal growth and development of plant is very low. Ni has been identified as a component of various enzymes in plants, various other biochemical, physiological and growth responses. The con...