Composites of nanometre-sized copper core–copper oxide (Cu-Cu2O) shell with different diameters were synthesized by a facile one step co-solvent technique. By the analysis X-ray diffraction (XRD) and transmission electron microscope (TEM) data, resultant particles confirmed to be pure nanocrystalline in nature. The perfect core-shell structure Cu-Cu2O was using high resolution TEM. presence Cu ...

Cu2O flower/grass-like nanoarchitectures (FGLNAs) were fabricated directly on two category specimens of Cu foils and Cu film using thermal oxidation method. The FGLNAs are approximately 3.5 to 12 μm in size, and their petals are approximately 50 to 950 nm in width. The high compressive stress caused by a large oxide volume in the Cu2O layer on the specimen surface played an important role in th...

In this work, copper oxides-based photocathodes for photoelectrochemical cells (PEC) were produced the first time by screen printing. A total 7 × 10−3 g/m2 glycerine trioleate was found as optimum deflocculant amount to assure stable and homogeneous inks, based on CuO nano-powder. The inks formulated considering different binder amounts deposited producing films with homogenous thickness, micro...

We report a synthetic approach to form cubic Cu2O/Pd composite structures and demonstrate their use as photocatalytic materials for tandem catalysis. Pd nanoparticles were deposited onto Cu2O cubes, and their tandem catalytic reactivity was studied via the reductive dehalogenation of polychlorinated biphenyls. The Pd content of the materials was gradually increased to examine its influence on p...

Copper alloys often used in cooling circuits of industrial plants can be affected by biocorrosion induced by biofilm formation. The objective of this work was to study the influence of protein adsorption, which is the first step in biofilm formation, on the electrochemical behavior of 70Cu-30Ni (wt.%) alloy in static artificial seawater and on the chemical composition of oxide layers. For that ...

Solar conversion devices are generally connected with energy storage systems to overcome the influence of sunlight variability. Developing an integrated solar and device is attractive approach compensate for loss directly connecting these separate devices. In this work, a photocapacitive developed based on Cu2O/CuO heterostructure, Cu2O as light absorber CuO providing platform electron ion stor...

Cu/Cu2O nano-heterostructure hollow spheres with a submicron diameter (200-500 nm) were prepared by a microwave-assisted hydrothermal method using Cu(OAc)2·H2O, PVP and ascorbic acid solution as the precursors. The morphology of the products could evolve with the hydrothermal time from solid spheres to thick-shell hollow spheres, then to thin-shell hollow spheres, and finally to nanoparticles. ...

Amidation of nitrile with N,N-dimethylformamide (DMF) was catalyzed by Cu2O with 1,10-phenanthroline as a ligand under an oxygen atmosphere. A variety of N,N-dimethyl benzamides were obtained in yields up to 84%.