Aerosol particulates collected on filters from ballistic penetration and erosion events for W-Ni-Co and W-Ni-Fe kinetic energy rod projectiles penetrating steel target plates were observed to be highly cytotoxic to human epithelial A549 lung cells in culture after 48 hours of exposure. The aerosol consisted of micron-sized Fe particulates and nanoparticulate aggregates consisting of W, Ni or W,...

Nickel-iron mixed metal oxyhydroxides have attracted significant attention as an oxygen evolution reaction (OER) catalyst for solar fuel renewable energy applications. Here, we performed surface-selective and time-dependent redox titrations to directly measure the surface OER kinetics of Ni(IV) and Fe(IV) in NiOOH, FeOOH, and Ni(1-x)Fe(x)OOH (0 < x < 0.27) electrodes. Most importantly, two type...

ÐWe analyse the development of shear bands in axisymmetric, thermomechanical deformations of a circular tungsten heavy alloy (WHA) rod impacting at normal incidence a smooth rigid target. The rod's material is modeled either as a mixture of Fe±Ni±W particles interspread randomly among the W-particles or as a homogeneous alloy. For comparison purposes we also analyse deformations of a pure W and...

Introduction: Fe (T1/2= 1.49 My) is a key a short-lived radioactive nuclide because it is the only one for which an origin from irradiation by cosmic rays is impossible. Fe is a neutron-rich nuclei and its production rate during irradiation processes around the early Sun (because of the low cross sections of appropriate reactions and of the low abundance of targets) is at least two orders of ma...

Nafion contamination by ferrous-alloy corrosion products, resulting in dramatic drops of the Ohmic potential, is a suspected major failure mode of polymer electrolyte membrane fuel cells that make use of metallic bipolar plates. This study demonstrates the potential of scanning transmission X-ray microscopy combined with X-ray absorption and fluorescence microspectroscopy for exploring corrosio...

The underlying physics of all ferromagnetic behavior is the cooperative interaction between individual atomic magnetic moments that results in a macroscopic magnetization. In this work, we use extreme ultraviolet pulses from high-harmonic generation as an element-specific probe of ultrafast, optically driven, demagnetization in a ferromagnetic Fe-Ni alloy (permalloy). We show that for times sho...

Uncovering the physical mechanisms that govern ultrafast charge and spin dynamics is crucial for understanding correlated matter as well as the fundamental limits of ultrafast spin-based electronics. Spin dynamics in magnetic materials can be driven by ultrashort light pulses, resulting in a transient drop in magnetization within a few hundred femtoseconds. However, a full understanding of femt...

Introduction: The 3.8 km in diameter Steinheim Basin (Baden-Württemberg, SW Germany) is a small, complex impact structure hosted by a sequence of Triassic to Upper Jurassic sandstones, marls, and limestones that build up the Swabian Alb plateau [1]. The specific alignment of the Steinheim Basin, the 24 km in diameter and 14.4 Ma Ries crater, and the Central European tektite strewn field led [2]...

Anaerobic CO dehydrogenases catalyze the reversible oxidation of CO to CO2 at a complex Ni-, Fe-, and S-containing metal center called cluster C. We report crystal structures of CO dehydrogenase II from Carboxydothermus hydrogenoformans in three different states. In a reduced state, exogenous CO2 supplied in solution is bound and reductively activated by cluster C. In the intermediate structure...

[NiFe]-hydrogenases generally carry the bimetallic Ni-Fe reaction center on their largest subunit. The [NiFeSe]-hydrogenase Vhu from Methanococcus voltae has an unusual subunit composition. Some of the amino acids participating in the formation of the reaction center are within a separate, very small subunit, called VhuU. It consists of only 25 amino acids and contains the selenocysteinyl resid...