Treatment of tetrakis(diethylamido)zirconium(IV); [Zr(NEt2)4] with a series of β-ketoimines ({[RHN]C(CH3)=C(H)C(CH3)=O} where R is a functionalized side-chain; 4-(2-methoxyethylamino)pent-3-en-2-one, Hmeap; 4-(3-methoxypropylamino)pent-3-en-2-one, Hmpap; 4-(2-(dimethylamino)ethylamino)pent-3-en-2-one, Hdeap; 4-(3-(dimethylamino)propylamino)pent-3-en-2-one, Hdpap) leads to an amine substitution ...

The discovery of superconductivity in magnesium diboride (MgB2: 39 K, in January 2001) (Nagamatsu et al., 2001) has generated enormous interest and excitement in the superconductivity community and the world in general, but especially among researchers into superconductivity in non-oxide and boron related compounds.

Background: Some Particular areas contain natural radionuclide at levels much higher than those usually present in earth's crust. The radiological impact of the use of zirconium ore in zirconium industry is due to internal exposure of the lung by alpha particles and external exposure of the body by the gamma rays. The result of gamma spectrometry measurement of the concentrations of th...

The physical, mechanical, and thermal properties of polycrystalline TiB2 are examined with an emphasis on the significant dependence of the properties on the density and grain size of the material specimens. Using trend analysis, property relations, and interpolation methods, a coherent set of trend values for the properties of polycrystalline TiB2 is determined for a mass fraction of TiB2 ⩾ 98...

The purpose of this study was to compare the fracture resistance and fracture mode of single implant-zirconium coping combinations using zirconium and titanium abutments and to analyze the stress distribution pattern using three-dimensional finite elements analysis. Twenty implants with titanium and zirconium abutments were randomly divided into two groups (n = 10) and into resin blocks. Zircon...

Aim: The aim of this in vitro study was to evaluate imaging artifacts induced by Titanium, Zirconium, Titanium-Zirconium abutments in CT, MRI and CBCT imaging modalities.Methods: A 4×8mm titanium fixture was inserted in a dry human mandible. Titanium, Zirconium and Titanium–Zirconium abutments measuring 10.5 mm in height are located on the fixture, one by one. Each abutment was scan...

The structure of solid zirconium tetrachloride is known from X-ray studies[l] to consist of extended chains of distorted octahedra with two bridging chlorine atoms between adjacent zirconium atoms. Although the unit cell possesses a center of symmetry, the two pairs of bridging chlorine atoms attached to a given zirconium atom are not trans to each other. The factor group symmetry thus is C2h w...

We already reported that an intramolecular benzylation of the imino moiety of bidentate iminopyrrolyl ligands afforded an amido-pyrrolyl complexes 1 and they exhibited better catalytic activity for ethylene polymerization compared to the corresponding bis(iminopyrrolyl) dichloro complexes of zirconium. In this contribution, we prepared amido-pyrrolyl complexes of zirconium (3a-d) and hafnium (4...

The magnetic behavior of iron sheathed magnesium diboride (MgB2) wires was investigated. Global magnetization measurements have shown unusual critical current density variations compare to a superconductor with no magnetic environment. Local quantitative studies, through MO images, are linked to these global magnetization measurements in order to better understand the observed results. It is sh...

IMPORTANCE Hyperkalemia is a common electrolyte abnormality that may be difficult to manage because of a lack of effective therapies. Sodium zirconium cyclosilicate is a nonabsorbed cation exchanger that selectively binds potassium in the intestine. OBJECTIVE To evaluate the efficacy and safety of zirconium cyclosilicate for 28 days in patients with hyperkalemia. DESIGN, SETTING, AND PARTIC...