Understanding the mechanism of cracking during the drying of aqueous colloidal dispersions is important to preventing film failure. While most of the reported work has dealt with stable aqueous dispersions, a few studies have focused on flocculated systems. The latter especially assumes importance because the role of particle packing in the mechanism of cracking is not completely understood. In...

When colloidal suspensions dry, stresses build up and cracks often occur -a phenomenon undesirable for important industries such as paint and ceramics. We demonstrate an effective method which can completely eliminate cracking during drying: by adding emulsion droplets into colloidal suspensions, we can systematically decrease the amount of cracking, and eliminate it completely above a critical...

Concrete and cracking are nearly synonymous despite our best efforts and intentions. Relationships between cracking and the stress states that lead to cracking can be instructive. In an effort to better understand these relationships, X-ray microtomography was used to make high-resolution three-dimensional digital images of small concrete specimens under load. Using 3D image analysis, quantitat...

Theoretical models are developed for heat conduction and thermal expansion in a fiber-reinforced ceramic cross-ply laminate containing an array of parallel transverse matrix cracks. Two stages of the transverse matrix cracks are considered : Stage-I with tunnel cracks in the 90” plies aligned parallel to the fibers, and Stage-II with cracks extended across both the 90 and 0” plies with intact f...

We postulate that dominant damage modes in a fiber-reinforced laminated composite are fiber breakage, matrix cracking, fiber/ matrix debonding, and delamination/sliding. The first three damage modes are represented by internal variables with their development governed by constitutive relations. The delamination/sliding failure mode is presumed to initiate at a point on an interface between two ...

Culture extends biology in that the setting of development shapes the traditions that individuals learn, and over time, traditions evolve as occasional variations are learned by others. In humans, interactions with others impact the development of cognitive processes, such as sustained attention, that shape how individuals learn as well as what they learn. Thus, learning itself is impacted by c...

The catalytic cracking method of PAHs for the pyrolysis gaseous products is proposed to control their pollution to the environment. In this study, the Py-GC-MS is used to investigate in situ the catalytic effect of CaO and Fe2O3 on the 16 PAHs from Pingshuo coal pyrolysis under different catalytic temperatures and catalyst particle sizes. The results demonstrate that Fe2O3 is effective than tha...

The kinetics of alkane cracking in zeolites MFI and FAU have been simulated theoretically from first principles. The apparent rate coefficient for alkane cracking was described as the product of the number of alkane molecules per unit mass of zeolite that are close enough to a Brønsted-acid site to be in the reactant state for the cleavage of a specific C-C bond and the intrinsic rate coefficie...

In this paper, the cyclic fatigue hysteresis loops of 2D woven SiC/SiC ceramic matrix composites (CMCs) at elevated temperatures in steam have been investigated. The interface slip between fibers and the matrix existing in matrix cracking modes 3 and 5, in which matrix cracking and interface debonding occurred in longitudinal yarns, is considered as the major reason for hysteresis loops of 2D w...