Arylamides of 3-hydroxy-2-naphthoic acid are widely used in the production organic azo pigments, as medicines and pesticides.
 Titanium tetrachloride, tetrabutoxytitanium polybutoxytitanates, previously for synthesis most important them., anilide by boiling latter aniline (184 °C), proved to be ineffective catalysts carrying out this reaction ortho-xylene.
 The study reasons inhibitio...

We report here a number of dianionic 1,4-diaza-1,3-butadiene complexes of titanium and zirconium synthesised by a salt metathesis reaction. The reaction of either CpTiCl3 or Cp2TiCl2 with the dilithium salt of N,N'-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene [; abbreviated (Dipp)2DADLi2] afforded the mono-cyclopentadienyl titanium complex [η(5)-CpTi((Dipp)2DAD)Cl] () bearing a dianionic ...

Inspired by the high adhesiveness of the electrospun fiber, we propose a method to fabricate multi-scale heterogeneous hump-on-string fiber via the adsorption of nanoparticles, the NPCTi which is the hydrolysate of titanium tetrachloride (TiCl₄) and the nanoparticles containing Al (NPCAl) which is produced by the hydrolysis of Trimethylaluminium (TMA, Al(CH₃)₃). The water collection efficiency ...

Anodic formation of titania nanowires has been interpreted using a bamboo-splitting model; however, a number of phenomena are difficult to explain with this model. Herein, transition from nanotubes to nanowires is investigated by varying the anodizing conditions. The results indicate that the transition requires a large number of hydrogen ions to reduce the passivated area of tube walls, and th...

In the recent years, great interest has been devoted to the unique properties of nanofluids. The dispersion process and the nanoparticle suspension stability have been found to be critical points in the development of these new fluids. For this reason, an experimental study on the stability of water-based dispersions containing different nanoparticles, i.e. single wall carbon nanohorns (SWCNHs)...

A series of titanium dioxide (TiO(2)/Ti) film electrodes were prepared from titanium (Ti) metal mesh by an improved anodic oxidation process and were further modified by photochemically depositing gold (Au) on the TiO(2) film surface as Au-TiO(2)/Ti film electrodes. The morphological characteristics, crystal structure and photoelectroreactivity of both the TiO(2)/Ti and Au-TiO(2)/Ti electrodes ...

The influence of halide ions on the photocatalytic process on titanium dioxide has been investigated carefully. Chloride and bromide ions, acting as hole scavengers, generate active radical species (e.g., ·Cl and ·Br) that participate in reactions with the organic compounds and the transient intermediates. Chloride and bromide ions have shown to deeply inhibit the degradation rate of chloroform...

The core-shell method is used as a novel synthetic process of micronized Ti-Zeolite Na-A which involves calcination at 700°C of coated Egyptian Kaolin with titanium tetrachloride in acidic medium as the first step. The produced Ti-coated metakaolinite is subjected to microwave irradiation at low temperature of 80°C for 2 h. The prepared micronized Ti-containing Zeolites-A (Ti-Z-A) is characteri...