A hybrid photoanode based on a molecular water oxidation precatalyst was prepared from TiO2-protected n- or p+-Si coated with multiwalled carbon nanotubes (CNT) and the ruthenium-based water oxidation precatalyst [RuIV(tda)(py-pyr)2(O)], 1(O) (tda2- is [2,2':6',2″-terpyridine]-6,6″-dicarboxylato and py-pir is 4-(pyren-1-yl)-N-(pyridin-4-ylmethyl)butanamide). The Ru complex was immobilized by π-...

Photoresponsive titania surfaces are of great interest due to their unique wettability change upon ultraviolet light illumination. However, their applications are often limited either by the inability to respond to visible light or the need for special treatment to recover the original wettability. Sensitizing TiO2 surfaces with visible light-absorbing materials has been utilized in photovoltai...

For the sustainable production of hydrogen by photocatalysis, the use of renewable resources such as water, organic compounds from plant biomass and earth abundant metal promoters is desired. We herein describe the previously not reported "one-pot" photoassisted synthesis of a binary metal-nitrogen promoted Cu(0)-N-TiO2 photocatalyst from a N-TiO2 precursor by photodeposition of copper directly...

The rutile TiO2(011) surface exhibits a (2 × 1) reconstruction when prepared by standard techniques in ultrahigh vacuum (UHV). Here we report that a restructuring occurs upon exposing the surface to liquid water at room temperature. The experiment was performed in a dedicated UHV system, equipped for direct and clean transfer of samples between UHV and liquid environment. After exposure to liqu...

The polyvinylidene fluoride (PVDF)/Fe 3+ -TiO2 catalytic membrane was prepared by sol-gel method. It was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), FT-IR spectrum (FT-IR), mechanics capability, water flux, pepsin retention, porosity and contact angle etc. The catalytic activity of PVDF/Fe 3+ -TiO2 catalytic membrane was evaluated by the degradation of refracto...

The photocatalytic oxidation of 4-methoxybenzyl alcohol to p-anisaldehyde (PAA) was performed in water with organic-free suspensions of home-prepared and commercial titanium dioxide (TiO2) catalysts. The nanostructured TiO2 samples were synthesised by boiling aqueous solutions of titanium tetrachloride (TiCl4), under mild conditions, for different times. The crystallinity increased with the boi...

Supported transition metals on TiO2 surfaces have shown exceptional catalytic properties in many important process such as CO oxidation, selective propane oxidation, hydrogenation, water adsorption and other catalytic and photocatalytic oxidation reaction at low-temperature. Among the three polymorphs of TiO2, the anatase crystal is the more photoactive. The anatase (101) surface attracts more ...

Conductive polypyrrole–polyaniline/TiO2 nanocomposites (PPy–PANI/TiO2) were prepared by in situ oxidative copolymerization of pyrrole and aniline monomers in the presence of TiO2. For comparison studies, polypyrrole/TiO2 (PPy/TiO2) and polyaniline/TiO2 (PANI/TiO2) were also prepared. The samples were characterized by X-ray diffraction, transmission electron microscopy, UV-vis diffuse reflectanc...