Responsive supramolecular gels were constructed from crown ether terminated four-arm star poly(epsilon-caprolactone) (PCL-DB24C8) and dibenzylammonium-terminated two-arm PCL-DBAS (see scheme), exploiting the formation of pseudorotaxane linkages between crown ether and ammonium moieties. The resultant supramolecular gels exhibit thermo- and pH-induced reversible gel-sol transition.

High Internal Phase Emulsion hydrogels are prepared from waterborne poly(N-isopropylacrylamide) nanogel dispersions which are non-covalently crosslinked through 2-ureido-4[1H] pyrimidinone (UPy) quadruple hydrogen bond groups. The reversible UPy crosslinks allow for the HIPE-hydrogels to be molded into objects which are thermo-responsive in nature.

Thermo-responsive diblock copolymers composed of hydrophilic methoxy poly(ethylene glycol) (MPEG) and hydrophobic biodegradable polyesters were prepared for application as injectable drug delivery systems, because they show a thermo-responsive sol-to-gel transition, especially around body temperature, when dispersed in aqueous solutions. The thermogelling hydrogels formed by hydrophobic aggrega...

In this paper, new numerical modeling of material flow in the thermo-mechanical friction stir welding process is presented. In this numerical model, the discretization in space is derived by the meshfree Galerkin method using a Lagrangian meshfree convex approximation. The discrete thermal and mechanical equations are weakly coupled as the time advances using a forward difference scheme. A mort...

Stimuli-responsive polymers show a sharp change in properties upon a small or modest change in environmental condition, e.g. temperature, light, salt concentration or pH. This behaviour can be utilised for the preparation of so-called 'smart' drug delivery systems, which mimic biological response behaviour to a certain extent. The possible environmental conditions to use for this purpose are li...

We demonstrate a novel platform to control the thermo-optic sensitivity in nanophotonic devices by evanescent coupling of light with bimaterial cantilevers. The cantilever can be designed to provide a negative thermal feedback to passively compensate for the positive thermo-optic effect in the waveguide core. We demonstrate athermal operation over 14 deg in cantilever coupled Silicon ring reson...

The analytical solution of functionally graded piezoelectric hollow cylinder which is under radial electric potential and non-axisymmetric thermo-mechanical loads, are presented in this paper. Using complex Fourier series and estimation of power law for variations of material characterizations through the thickness, the electro thermo mechanical behavior of the FGPM cylinder is obtained. The st...

Abstract Thermo‐responsive polymers have been widely explored because of their diverse structures and functions in response to temperature stimuli. Great attention has attracted exploring designing such composites, which offer tremendous opportunities build up a systematic understanding structure–function relationships pave the ways for extensive applications electronics, soft robotics, electro...

Abstract The possibility of accurately identifying thermal material parameters on the basis a simple tension test is presented, using parameter identification framework for thermo-mechanically coupled models full field displacement and temperature measurements. Main objective to show impact model formulation results such an with respect accuracy uniqueness result. To do so, as proof concept, da...