نتایج جستجو برای: symmetric catalyst
تعداد نتایج: 124781 فیلتر نتایج به سال:
Recently, some authors proposed the use of symmetric weightsfor computing the elements of cross-efficiency matrix. In spite ofthe fact that the proposed method decreases the number of zeroweights, a large number of zero weights may still exist among inputand output symmetric weights. To decrease the number of input andoutput symmetric weights, this paper improves the proposed secondarygoal mode...
The effect of modifying the N-aryl substituent (aryl = mesityl vs. m-xylyl) of the phosphinoamide ligands linking Zr and Co in tris(phosphinoamide)-linked heterobimetallic complexes has been investigated. Treatment of the metalloligand ((i)Pr2PNXyl)3ZrCl (2) (Xyl = m-xylyl) with CoI2 affords the iodide-bridged product ICo((i)Pr2PNXyl)2(μ-I)Zr(η(2-i)Pr2PNXyl) (3) rather than the C3-symmetric iso...
We study coupled irreversible processes. For linear or linearized kinetics with microreversibility, ẋ=Kx, the kinetic operator K is symmetric in the entropic inner product. This form of Onsager’s reciprocal relations implies that the shift in time, exp(Kt), is also a symmetric operator. This generates the reciprocity relations between the kinetic curves. For example, for the Master equation, if...
A triethylaluminium(TEAl)-modified Phillips ethylene polymerisation Cr/Ti/SiO2 catalyst has been developed with two distinct active regions positioned respectively in the inner core and outer shell of the catalyst particle. DRIFTS, EPR, UV-Vis-NIR DRS, STXM, SEM-EDX and GPC-IR studies revealed that the catalyst produces simultaneously two different polymers, i.e., low molecular weight linear-ch...
The c-Myc protein is dysregulated in many human cancers and its function has not been fully elucitated yet. The c-Myc inhibitor Omomyc displays potent anticancer properties in animal models. It perturbs the c-Myc protein network, impairs c-Myc binding to the E-boxes, retaining transrepressive properties and inducing histone deacetylation. Here we have employed Omomyc to further analyse c-Myc ac...
The conditions under which, multilinear forms (the symmetric case and the non symmetric case),can be written as a product of linear forms, are considered. Also we generalize a result due to S.Kurepa for 2n-functionals in a group G.
Protein arginine methyltransferases (PRMTs) catalyze the transfer of the methyl group from S-adenosyl-l-methionine (AdoMet) to arginine residues. There are three types of PRMTs (I, II and III) that produce different methylation products, including asymmetric dimethylarginine (ADMA), symmetric dimethylarginine (SDMA) and monomethylarginine (MMA). Since these different methylations can lead to di...
Platinum group metal-free (PGM-free) catalyst with different loadings was investigated in air breathing electrodes microbial fuel cells (MFCs). Firstly, the electrocatalytic activity towards oxygen reduction reaction (ORR) of the catalyst was investigated by rotating ring disk electrode (RRDE) setup with different catalyst loadings. The results showed that higher loading led to an increased in ...
An efficient, novel bifunctional C2-symmetric ionic liquid–supported (S)-proline organocatalyst 7 was developed for a one-pot, five-component reaction involving ?-keto esters 8, aryl aldehydes 9, and amines 10, affording highly functionalized tetrahydropyridines 11a–o by simultaneous generation of fives bonds two stereogenic centers with extraordinary diastereo- enantioselectivities (up to >...
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