Japan Several patterned growth techniques of single-walled carbon nanotubes (SWNTs) by modifing the dip-coating process are discussed. The conventional concept of using SiO2 patterned Si substrates to selectively grow 3D carbon nanotube structures can be applied to a dip-coating method followd by alcohol CVD growth. High-quality vertically aligned single-walled carbon nanotube (SWNT) patterns c...

The cytotoxic response of cells in culture is dependant on the degree of functionalization of the single-walled carbon nanotube (SWNT). After characterizing a set of water-dispersible SWNTs, we performed in vitro cytotoxicity screens on cultured human dermal fibroblasts (HDF). The SWNT samples used in this exposure include SWNT-phenyl-SO(3)H and SWNT-phenyl-SO(3)Na (six samples with carbon/-phe...

Conformal atomic layer deposition ~ALD! on as-grown suspended single-walled carbon nanotubes ~SWNTs! is not possible due to the inertness of ALD precursor molecules to the SWNT surface. Here, we present a functionalization technique that makes SWNTs reactive with ALD precursors, and deposit high-k oxides ~Al2O3 and HfO2! onto the nanotubes to illustrate this method. Reactivity of the precursors...

Spectrofluorimetric measurements on single-walled carbon nanotubes (SWNTs) isolated in aqueous surfactant suspensions have revealed distinct electronic absorption and emission transitions for more than 30 different semiconducting nanotube species. By combining these fluorimetric results with resonance Raman data, each optical transition has been mapped to a specific (n,m) nanotube structure. Op...

Vertical single-walled and double-walled carbon nanotube (SWNT and DWNT) arrays have been grown using a catalyst embedded within the pore walls of a porous anodic alumina (PAA) template. The initial film structure consisted of a SiOx adhesion layer, a Ti layer, a bottom Al layer, a Fe layer, and a top Al layer deposited on a Si wafer. The Al and Fe layers were subsequently anodized to create a ...

Leveraging the unique properties of single-walled carbon nanotube (SWNT) intramolecular junctions (IMJs) in innovative nanodevices and next-generation nanoelectronics requires controllable, repeatable, and large-scale preparation, together with rapid identification and comprehensive characterization of such structures. Here we demonstrate SWNT IMJs through directly growing ultralong SWNTs on tr...

This paper studies the pure bending and bending-induced local buckling of a nanocomposite beam reinforced by a single-walled carbon nanotube (SWNT). The Airy stress-function method was employed to analyse the deformation of the matrix, and the cross-sectional change of the SWNT in bending was taken into account. A particular consideration was given to the effect of the SWNT s radial flexibility...

Address correspondence to [email protected] ABSTRACT Density functional theory (DFT) and tight binding (TB) models have been used to study systems containing single-walled carbon nanotubes (SWNTs) and metal clusters that are of relevance to SWNT growth and regrowth. In particular, TB-based Monte Carlo (TBMC) simulations at 1000 or 1500 K show that Ni atoms that are initially on the surface of th...

Results are presented of in situ studies of the thermoelectric power and four-probe resistance of single-walled carbon nanotube films during the adsorption of cyclic hydrocarbons C(6)H(2n) (n=3-6). The size of the change in these transport parameters is found to be related to the pi electron population of the molecule, suggesting the coupling between these pi electrons and those in the nanotube...

Transport measurements on a bundle of single-walled carbon nanotubes have been made below 4.2 K as a function of side gate and source–drain bias voltage. The transport of an individual nanotube is described by the Coulomb blockade effect. The zero-dimensional quantum states of the nanotube become clear for measurements of large bias voltage. In addition, we present preliminary results of microw...