The influence of solution pH (in the range 3-9) on the adsorption of polyacrylic acid (PAA) on the mixed silica-alumina surface (SA-3: SiO2 97 %-Al2O3 3 % and SA-96: SiO2 4 %-Al2O3 96 %) was investigated. The following methods were applied in experiments: spectrophotometry, viscosimetry, potentiometric titration, and microelectrophoresis, which enable determination of adsorbed amount of the pol...

This paper describes the adsorption of two organic (acetic and citric) acids on the blast furnace sludge, a representative by-product of the steelmaking industry. By PIXE, XRD, BET and SEM methods, it was shown that blast furnace sludge is a complex heterogeneous material with a specific surface area of s = 31.46 m g, composed mainly of amorphous phase (w = 76.2 %), calcite (w = 9.9 %), magneti...

This study investigates the effect of surface acidity and basicity of aluminas on asphaltene adsorption followed by air oxidation. Equilibrium batch adsorption experiments were conducted at 25°C with solutions of asphaltenes in toluene at concentrations ranging from 100 to 3000 g/L using three conventional alumina adsorbents with different surface acidity. Data were found to better fit to the F...

Lattice gas automata (LGA) model is developed to simulate polymer adsorption process by adding some collision rules. The simulation result of the model is matched with batch experiment and compared with accepted isothermal adsorption equations. They show that the model is viable to perform simulation of the polymer adsorption process. The LGA model is then applied for simulating continuous poly...

Boron is a plant nutrient essential for adequate plant growth, yet the range between B deficiency and toxicity levels is rather narrow. Boron adsorption reactions with soil components, particularly sesquioxides, most often regulate the amount of B in the soil solution. The reaction mechanisms of B adsorption on oxides have not been fully characterized, however. Pressure-jump relaxation experime...

Many drug delivery systems suffer from undesirable interactions with the host immune system. It has been experimentally established that covalent attachment (irreversible adsorption) of suitable macromolecules to the surface of the drug carrier can reduce such undesirable interactions. A fundamental understanding of the adsorption process is still lacking. In this paper, the classical random ir...

A time-resolved evanescent wave absorption technique is employed in studying the adsorption of a mammalian protein (cytochrome c) from an electrolyte-free solution on a hydrophilic glass surface. The method combines the sensitivity of a fast-scan spectral analyzer and surface specificity of slab optical waveguide (SOWG) technique. While proteins are viewed to undergo an overall irreversible ads...

Chemical modifications of clay to remove methylene blue (MB) from aqueous solutions at room temperature were compared. Natural bentonite (NC) was modified by cation exchange with hexadecyltrimethylammonium chloride (HC), bencyltriethylammonium chloride (BC), and tetramethylammonium chloride (TC) to reverse the surface polarity of the hydrophilic bentonite. The adsorption of MB was studied and f...

Predicting protein adsorption from solution to a surface is a perennial problem in biomedicine and related fields. Despite constant attention in the literature, it is not currently possible to predict quantitatively the amount of adsorbed protein given environment, protein and surface parameters. In previous work, we presented the Biomolecular Adsorption Database, an online collection of protei...

The adsorption of dilute long polymers of length N dissolved in a semi-dilute solution of shorter chains of length P is considered using a scaling approach. The short chains themselves are considered as non-adsorbableTwo qualitatively different phase diagrams in the concentration adsorption-strength diagram are predicted depending on the value of N/P~. An overall concentration and chain length ...