Aiming at an improved knowledge of the formation of the solid electrolyte interphase (SEI), as basis for the safe and efficient use of new anode materials, we investigated the SEI formation on silicon and lithium titanate (LTO) anodes by electrochemical impedance spectroscopy (EIS) and ex situ X-ray photoelectron spectroscopy (XPS) measurements. While the EIS measurements performed at equidista...

to improve the corrosion protection of copper metal, 0.01m concentration of 1h-1,2,4-triazole-3-thiol (tat) was incorporated into the hybrid sol-gel monolayers containing 3-glycidoxypropyltrimethoxysilane (gptms) and tetraethoxysilane (teos). it was further subjected to hydrolysis and condensation reaction to form a sol-gel matrix. the tat-doped hybrid sol-gel coating was applied over the coppe...

vanillin is an interesting corrosion inhibitor because of its safe use and high solubility inwater. the effect of vanillin on the corrosion inhibition of carbon steel in 1.0 mhydrochloric acid solution has been studied using potentiodynamic polarization,electrochemical impedance spectroscopy (eis) and electrochemical noise (en) techniques.the effect of temperature on the rate of corrosion in th...

Y1.86Eu0.14WO6 phosphors were prepared using a solid-state reaction method. Their optical properties were analysed, and they was mixed with TiO2, sintered, and used as a photoelectrode (PE) in dye-sensitized solar cells (DSSCs). The as-prepared photoelectrode was characterized by photoluminescence spectroscopy, diffuse reflectance, electrochemical impedance spectroscopy (EIS) and X-ray diffract...

The corrosion behavior of oxygen-free copper in anoxic sulfide solutions under nuclear waste disposal conditions was studied using electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) equipped with a focused ion beam (FIB), X-ray photoelectron spectroscopy (XPS) and Micro X-ray diffraction ( XRD). The film growth process and mechanism were elucidated using an Au mark...

The dynamic behaviors of oxide layer formation, growth and self-healing in liquid metal lead (Pb) were studied by on-line monitoring with electrochemical impedance spectroscopy (EIS). rod made zirconium (Zr) was immersed to Pb at 773 K as the working electrode EIS. capacitance semicircle due formation on surface detected EIS after immersion for 45 hr. increase continuously detected. taken out f...

vanillin offers interesting possibilities for corrosion inhibition because of its safe use and highsolubility in water. the effect of vanillin on the corrosion inhibition of aisi 304 stainless steel in0.5m h2so4 solution has been studied using potentiodynamic polarization and electrochemicalimpedance spectroscopy (eis). furthermore, this paper demonstrates that the electrochemical noise(en) tec...

The biodegradable inhibitors, which could effectively reduce the rate of corrosion of carbon steel, were investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The mixed-type inhibitors extracted from Eriobotrya japonica Thunb. leaf exhibited excellent inhibition performance, and the inhibition efficiency for carbon steel reached 90.0% at 298 K in hydroch...

Electrochemical reduction of complexes of monochlorosilanes with redox-active ligands such as 2,2'-bipy occurs in one-electron fashion at moderately negative potentials, E @ -1 V vs SCE (in CH3CN/0.1 M Bu4NBF4), leading to silyl radicals. These radicals, trapped with a-phenyl-N-tbutyl-nitrone and characterized as spin-adducts by ESR spectroscopy, add to carbon interfaces (glassy carbon, graphit...