It is common knowledge that light fluids rise while heavy fluids sink in the gravity field. The most obvious case is the isothermal Rayleigh-Taylor instability when a heavy fluid is placed on top of a light one. In the nonisothermal case, while heating from above, the density stratification is stable in a pure liquid. However, unstable density stratification might be established in a binary mix...

It has been recently recognized that the nonisothermal conditions present in physical vapor transport ampoules can give rise to a slip flow of gas over the side walls of the ampoule. This phenomenon, known as thermal creep, is usually insignificant relative to buoyancy-induced flows under similar nonisothermal conditions, and has therefore been neglected in previous PVT numerical models. Howeve...

Three-dimensional time-dependent numerical calculations are performed in a cubic cell filled with a binary mixture of water (90%) and isopropanol (10%). The system is heated from above while the Soret coe‰cient ðSTÞ is negative, i.e., a thermally stable Rayleigh–Benard configuration. Due to the Soret e¤ect, the heavier liquid is accumulated on the top of the lighter one and buoyant convection c...

The analysis in this communication addresses the unsteady MHD flow of tangent hyperbolic liquid through a vertical plate. model on mass and heat transport is set up with Joule heating, generation, viscous dissipation, thermal radiation, chemical reaction Soret-Dufour form partial differential equations (PDEs). PDEs are simplified into dimensionless by utilizing suitable quantities. solved spect...

Circular dichroism and difference ultraviolet visible spectra were obtained for cobalt hemoglobin derivatives. At 287 nm the ellipticity difference between the oxy- and deoxycobaltohemoglobin is about one-half as great as that for the native proteins indicating smaller quaternary conformational changes for the former. Deoxygenation increases the Soret rotational strengths of both iron and cobal...

Kinetics of the reaction of peroxynitrite with ferric cytochrome c in the absence and presence of bicarbonate was studied. It was found that the heme iron in ferric cytochrome c does not react directly with peroxynitrite. The rates of the absorbance changes in the Soret region of cytochrome c spectrum caused by peroxynitrite or peroxynitrite/bicarbonate were the same as the rate of spontaneous ...

A shadowgraph optical setup is used to study the time evolution of Soret induced convection in a colloidal suspension. We obtain a scale invariant behavior for the solutal Nusselt number as a function of the Rayleigh number. In a typical Rayleigh-Bénard experiment a horizontal slab of a fluid is contained between a top and bottom plates maintained at two different temperatures (higher temperatu...

The thermosolutal instability problem in a horizontal layer of an elasticoviscous nanofluid in porous medium is considered. Walters’ (model B') fluid model is employed to describe the rheological behavior of the nanofluid and for the porous medium, the Darcy model is employed. From the linear stability analysis based upon normal modes analysis method, the dispersion relation accounting for the ...

Abstract In this article, we analyze the entropy analysis in unsteady hydromagnetic flow of a viscous fluid over stretching surface. The energy attribute is scrutinized through dissipation, heat source/sink, and radiation. Furthermore, diffusion-thermo thermo-diffusion behaviors are analyzed. physical description rate discussed second law thermodynamics. Additionally, binary chemical reaction c...

Myoglobin from the dark muscle of sardine (Sardinella gibbosa) with the molecular weight of 15.3 kDa was isolated and characterized. The different myoglobin derivatives exhibited varying thermal unfolding characteristics. Deoxymyoglobin showed a single distinct endothermic peak at 74.5°C, whereas two transition temperatures were noticeable for oxymyoglobin (64.5°C and 78.4°C) and metmyoglobin (...