• The Bass model is widely used in business innovation and marketing research. It can function as a breakthrough curve model. outperforms the Bohart–Adams Modified describe highly asymmetric curves.

Abstract The present study aims at development of a mathematical model for the fixed-bed column adsorption that relates reactor parameters with breakthrough curve. Effects operating like bed height, flow rate, initial adsorbate concentration on were investigated by using various curves. arbitrary constants developed found to be dependent kinetics. proposed showed incredible results (Breakthroug...

We examine statics and dynamics of phase-separated states of dilute binary mixtures using density functional theory. In our systems, the difference of the solvation chemical potential between liquid and gas [Formula: see text] (the Gibbs energy of transfer) is considerably larger than the thermal energy [Formula: see text] for each solute particle and the attractive interaction among the solute...

This paper presents the results of a study aimed at estimating groundwater pollution source location from observed breakthrough curves using neural networks. Two different methods of presenting the breakthrough curves to the ANN are investigated. The feed-forward multi-layer perceptron (MLP) type artificial neural network (ANN) models are employed. The ANNs were trained using the back-propagati...

A mechanism of the solute retention in gas-liquid chromatography has been studied in the nonpolar hydrocarbon solute-polar stationary liquid phase system. N,N,N',N'-tetrakis(2-hydroxyethyl)ethylene diamine (THEED) was used as a polar stationary liquid phase. A dependence of the retention volume of the solutes and of the specific surface area of the liquid-coated, modified alumina upon the liqui...

Microbial breakthrough curves of 12 soils, generated by the application of dairy shed effluent followed by continuous artificial rainfall for one pore volume at 5 mm h(-1) onto large undisturbed soil cores, have been ranked as high, medium, or low potential for microbial bypass flow. The ranking is based on the position of the peak in the breakthrough curve. Knowledge of soil properties that af...

Laboratory tracer experiments were conducted to investigate solute transport in 12.5-m long, horizontally placed soil columns during steady saturated water flow. Two columns having cross-sectional areas of 10 x IOcm’ were used: a uniformly packed homogeneous sandy column and a heterogeneous column containing layered, mixed, and lenticular formations of various shapes and sizes. The heterogeneou...

The biosorption of copper by inactivated biomass of the brown seaweed Sargassum baccularia, immobilized onto polyvinyl alcohol (PVA) gel beads, was investigated using a laboratory-scale packed bed column. Continuous-flow column tests were performed to determine breakthrough curves at two different column lengths. In both cases, a very broad trailing edge of the breakthrough curve was observed, ...

This study was conducted to determine the significance of bromacil transport as a function of water and carbon content in soils and to explore the implications of neglecting sorption when making assessments of travel time of bromacil through the vadose zone. Equilibrium batch sorption tests were performed for loamy sand and sandy soil added with four different levels of powdered activated carbo...

Understanding the dynamics of fixed-bed adsorption columns for modeling is a demanding task due to the strong nonlinearities in the equilibrium isotherms, interference effects of competition of solutes for adsorbent sites, mass transfer resistances between fluid phase and solid phase, and fluid-dynamic dispersion phenomena. The interplay of these effects produces steep concentration fronts, whi...