We here report on the first example of an aptamer-based potentiometric sandwich assay of proteins. The measurements are based on CdS quantum dot labels of the secondary aptamer, which were determined with a novel solid-contact Cd2+-selective polymer membrane electrode after dissolution with hydrogen peroxide. The electrode exhibited cadmium ion detection limits of 100 pM in 100 mL samples and o...

Biomass materials are promising precursors for the production of carbonaceous materials due to their abundance, low cost and renewability. Here, a freestanding wrinkled carbon membrane (WCM) electrode material for flexible supercapacitors (SCs) was obtained from flower petal. The carbon membrane was fabricated by a simple thermal pyrolysis process and further activated by heating the sample in ...

DOI: 10.1002/aenm.201501590 electrochemical stability window, and (3) chemical compatibility with the anode and cathode. In the past few years, major advances have been achieved in increasing the Li ionic conductivity of the solid electrolytes. The state-of-the-art solid electrolyte materials, such as Li-garnet Li7La3Zr2O12 (LLZO) and Li10GeP2S12 (LGPS) have achieved an ionic conductivity of 10...

The impedance measurement between a pair of flush-mounted electrodes was used to measure the characteristics of a stratified near-wall bubbly flow. The variation in cross electrode impedance with liquid layer thickness and mixture void fraction was examined using numerical simulations and static experiments. The experimental realization of the measurement system was used to measure the solid fr...

The general purpose of our research program is to study problems relating to the atomic, molecular, and electronic processes occurring at gas -solid interfaces. Examples of these processes are: thermionic emission, surface ionization, adsorption, absorption, oxidation, catalysis by metals, electrode processes in electrical discharges, and the scattering of molecular beams from solid surfaces. S...

This paper reviews different modification methods to cathode, anode and electrolyte materials in view of their electrochemical properties for application in lithium/sulfur batteries. In the sulfur electrode, carbonaceous materials, conductive polymer materials, and metal oxide adsorbing materials are employed to enhance conductivity and reduce polysulfide dissolution. The effects of anodes and ...

A redox-reversible iron orthovanadate cathode is demonstrated for a solid oxide electrolyser with up to 100% current efficiency for steam electrolysis. The iron catalyst is grown on spinel-type electronic conductor FeV2O4 by in situ tailoring the reversible phase change of FeVO4 to Fe+FeV2O4 in a reducing atmosphere. Promising electrode performances have been obtained for a solid oxide steam el...

A thiocyanate ion selective poly(aniline) solid contact electrode based on manganese complex of N,N’-bis-(4-phenylazosalicylidene)-o-phenylene diamine ionophore was successfully developed. The electrode exhibits a good linear response of 58.1 mV/decade (at 20 ̊C ± 0.2 ̊C, r = 0.998) with in the concentration range of 1 × 10 ~ 1 × 10 M thiocyanate solution. The composition of this electrode was: i...

Approximation methods are often used in porous electrode models to eliminate the need to solve the local solid phase diffusion equation. These ethods include Duhamel’s superposition method, a diffusion length method and a polynomial approximation method which have long been used n the literature. The pseudo steady state (PSS) method is a method that has been used recently to develop a solution ...

There is currently a need for a reliable solid-state reference electrode, especially in applications such as autonomous sensing or long-term environmental monitoring. We present here for the first time a novel solid-state nanofiber junction reference electrode (NFJRE) incorporating a junction consisting of poly(methyl methacrylate) and carbon graphene stacked nanofibers. The NFJRE operates by u...