Rietveld analyses of neutron diffraction data collected on a series of Pb(Zr0.5Ti0.5)O3 samples, which had been prepared by sol-gel and conventional mixed oxide methods, showed that each sample contained both rhombohedral and tetragonal PZT (Pb[Zr1-xTix]O3). The zirconium-to-titanium ratio in the two phases was found to be markedly different. Pair distribution functions were also calculated for...

The hydrosilylation reaction is a dominant curing method for the light-emitting diode (LED) silicone encapsulant, which requires characteristics of high transparency, high refractive index, and thermal stability against the LED junction temperature. In this research, we synthesized a hydrogen containing oligosiloxane resin through non-hydrolytic sol–gel condensation. Methyldiethoxysilane (MDES)...

The sol-gel technique is earning the worldwide attention of researchers in the field of material science, due to its versatility in synthesizing inorganic ceramic materials at mild conditions. High purity, homogeneity, controlled porosity, stable temperature and nanoscale structuring are the most remarkable features offered by this method for generating highly sensitive and selective matrices t...

Abstract. In present paper, various industrial applications of the sol-gel technology will be briefly introduced. In particular, the current development status and technological issues of sol gel derived functional nanoparticles in electronic and industrial materials will be reviewed. Productions and surface modifications of nanoparticles by sol-gel processing, their incorporations into nanocom...

Grifolan is an antitumor (13)-ƒÀ-D-glucan with a ƒÀ-glucosyl substitution at C-6 of every three main chain units, and is produced by Grifola frondosa. Grifolan possesses two different solid-state conformations, N (native) and H (helix) (N. Ohno et al., Chem. Pharm. Bull., 34, 2555 (1986)), and both form a gel in an aqueous neutral media. In this study, the gel-to-sol or sol-to-gel transition of...

Ag/TiO2 photocatalytic nanoparticles by two methods, the sol – gel using a reducing agent and spattering was produced. Crystalline phase of Titanium dioxide was investigated in both. Ag/Tio2 peak in the sol – gel method at temperatures of 300,500 and 6000c were studied. Ag/TiO2 peak at different temperatures were determined using the spattering. XRD p...

Using sol-gel technology, a porous glass matrix (xerogel) is formed in a capillary column and acts as a support for a stationary phase of chromatographic particles used in capillary electrochromatography. Preparation of the sol-gel matrix and immobilization of the octadecylsilica (ODS) stationary phase occur in a single step. The presence of the particles in the column greatly reduces matrix cr...

A novel open-tubular CEC column coated with chitosan-graft-(β-CD) (CDCS) was prepared using sol-gel technique. In the sol-gel approach, owing to the 3D network of sol-gel and the strong chemical bond between the stationary phase and the surface of capillary columns, good chromatographic characteristics and unique selectivity in separating isomers were shown. The column efficiencies of 55,000∼16...