The four derivatives of isoquinoline-1,3-dione based on β-lactum (I-IV), have been explored as neutral ionophores for preparing poly(vinylchloride) based polymeric membrane electrodes (PME) selective to silver(I) ions. The addition of sodium tetraphenylborate (NaTPB) and dioctylsebacate (DOS) as a plasticizer was found to improve the performance of ion selective electrodes. The best performance...

Chloride analysis employing a coulometric technique is a wellestablished method. However, the equipment needed is specialized and somewhat expensive. The purpose of this paper is to report the development of the hardware and software to perform this analysis using an Apple computer to control the coulometric titration, as well as to automate it and to print out the results.The Apple computer is...

bioleaching processes for extraction of cu and mo from molybdenite cons. are more environmentally friendly and consume less energy than conventional technologies, yet less economically efficient. one necessary step towards arriving at a cost-effective bioleaching process is using appropriate methodology to optimize pertinent factors in such processes. to this end, the present study employed res...

A new device for removing silver points was evaluated. The instrument consists of a trepan bur to expose the end of the silver point and a hollow tube which fits over the exposed tip and is bonded to it with cyanoacrylate adhesive. Twenty groups with 10 extractors and silver points in each group were tested for adhesive strength with respect to overlap between extractor and silver point, snugne...

The importance of neurofibrillar impregnations in the study of the nervous system needs no emphasis. However, the silver methods currently used involve such a complex of variables that the results are by no means constant. The present communication is devoted to the problem of interpretation of results, together with certain fundamental relations between brain tissue and silver solution. The mo...

A method for sensitive and selective determination of silver based on the catalytic effect of silver(I) ion on the oxidation of Janus Green by peroxodisulfate is described. o-Phenanthroline is used as an activator. The rate of the decrease in absorbance of Janus Green (at 615 nm) is proportional to the concentration of silver in the range of 0.3-4.0 ng mL(-1) and 4.0-500.0 ng mL(-1). The theore...

Ionic silver has a long history as an antimicrobial in human health care. This article is a review of the published literature on how ionic silver may enter the body from exposure to silver-containing wound care products and its eventual metabolic fates, in an assessment of the safety during normal use of these products in wound care. Following the application to breached skin, there appears to...

A development program is underway at the IGISOL (Ion Guide Isotope Separator On-Line) facility, University of Jyväskylä, to efficiently and selectively produce low-energy radioactive ion beams of silver isotopes and isomers, with a particular interest in N=Z Ag. A hot cavity ion source has been installed, based on the FEBIAD (Forced Electron Beam Induced Arc Discharge) technique, combined with ...

A kinetic-spectrophotometric procedure is reported for determination of trace amounts of Ag(I). This method is based on catalytic effect of silver ion on the oxidation of congo red by potassium peroxodisulphate at pH=3.4 and 30 oC in the presence of 1,10-phenanthroline as an activator. The reaction was followed spectrophotometrically by measuring the rate of change in absorbance ...