A method to prepare novel organic-inorganic hydrophobic nanocomposite films was proposed by a site-specific polymerization process. The inorganic part, the core of the nanocomposite, is a ternary SiO₂-Al₂O₃-TiO₂ nanoparticles, which is grafted with methacryloxy propyl trimethoxyl silane (KH570), and wrapped by fluoride and siloxane polymers. The synthesized samples are characterized by transmis...

OBJECTIVE To investigate the repair potential of CAD/CAM (computer-aided design/computer-aided manufacturing) ceramic and composite blocks using a silane-containing bonding agent with different repair protocols. MATERIALS AND METHODS Twenty-four discs were constructed from CAD/CAM ceramic and composite blocks. The discs were divided into six groups according to surface pre-treatment employed;...

Biopolymers are easily denatured by heating, a change in pH or chemical substances when they are immobilized on a substrate. To prevent denaturation of biopolymers, we developed a method to trap a polynucleotide on a substrate by hydrogen bonding using silica particles with surfaces modified by aminoalkyl chains ([A-AM silane]/SiO2). [A-AM silane]/SiO2 was synthesized by silane coupling reactio...

objective:   the aim of this study was to evaluate the bond strength between metal brackets and non-glazed ceramic with three different surface treatment methods. materials and methods: forty-two non-glazed ceramic disks were assigned into three groups. group i and ii specimens were etched with 9.5% hydrofluoric acid. subsequently in group i, silane and adhesive were applied and in group ii, bo...

zinc oxide nano-particles with the average diameter of about 25 nm were modified with different mole ratios of trimetoxyvinyl silane (tmvs) and oleic acid, as coupling agents, in order to modify their surface properties and render them more hydrophobic. then, dispersibility of the surface modified nano-particles was examined in some monomers with different levels of hydrophobicity, including me...

Organosilanes are candidates to replace chromates as metal surface pretreatments to inhibit corrosion. Current research shows that silane films are strictly water barriers and show no electrochemical corrosion inhibition. To improve the corrosion performance of silane film, therefore, the foremost objective is to improve water resistance. An understanding the interaction of silane with water is...

Si, Xe and C NMR is used to investigate a porous material consisting of nano-sized ZnO particles coated by silane molecules. These materials are synthesized by a novel sol–gel procedure where the nanoscale ZnO particles are formed in the presence of the coating material 3-methacryloxypropyl-trimethoxysilane (‘‘silane’’). The BET specific surface of the uncoated particles, synthesized by the sam...

Nanoscale organofunctional silanes have been developed, tested and successfully applied to protect stone buildings in Europe against climatic effects since the 1860s. The same nanotechnologies can also be used pavement engineering create strong chemical bonds between a stabilising agent granular material. attachment of silane material changes surface become hydrophobic, thereby considerably red...

Soft lithography was used to replicate nanoscale features made using electron beam lithography on a polymethylmethacrylate (PMMA) master. The PMMA masters were exposed to fluorinated silane vapors to passivate its surfaces so that polydimethylsiloxane (PDMS) did not permanently bond to the master. From scanning electron microscopy, the silanization process was found to deposit a coating on the ...

AIM To compare the effect of different chemical solvents on glass fiber reinforced posts and to study the effect of these solvents on the shear bond strength of glass fiber reinforced post to core material. MATERIALS AND METHODS This study was conducted to evaluate the effect of three chemical solvents, i.e. silane coupling agent, 6% H2O2 and 37% phosphoric acid on the shear bond strength of ...