On the basis of nine periodical measurements, emissions of PCDD/F have been analysed. As a result, a correlation was detected between elevated PCDD/F emissions and operational problems with selective catalytic reduction (SCR) system. The air pollution control system (APCS) consisted of dry scrubbing system (mixture of active carbon and NaHCO3), fabric filter, DeNOx catalyst and wet scrubber. It...

Selective and rapid reductLon of nitro compounds is still area of considerable synthetic interestl, particularly when a molecule has several other reducible moieties. Numerous new reagents*-l4 have been developed for reduction of aromatic nitro compounds, however little attention has been paid to the reduction of aliphatic nitro compound&ry,S, which are traditionally reduced by high pressure ca...

A novel palladium promoted Ag/Al2O3 catalyst (denoted Ag-Pd/Al2O3) has been developed for the selective catalytic reduction of NO by C3H6. The Ag-Pd/Al2O3 shows a higher NOx conversion than Ag/Al2O3, especially at the temperatures ranging from 300 to 450 ◦C. The addition of a small amount of Pd (0.01 wt.%) to Ag/Al2O3 is considered to be favorable for the partial oxidation of C3H6. In situ diff...

Catalytic thermolysis is considered to be an effective process for viscosity reduction, the conversion of high-molecular components oil (resins and asphaltenes) into light hydrocarbons, desulfurization hydrocarbons. In this paper, we conducted non-catalytic catalytic a heavy sample isolated from Ashalcha field (Tatarstan, Russia) at temperature 250 °C. Fullerene C60 nanoparticles were applied p...

A series of cobalt containing alumina pillared zirconium phosphate materials have been prepared by ion exchange or by impregnation, and fully characterised. The catalytic behaviour of these materials in the selective catalytic reduction of NO by propane, in excess of oxygen, at temperatures ranging between 350 and 550 degrees C, has been also evaluated. A maximum NO conversion close to 14% is o...

Introduction Combustion in excess oxygen, as in dieseland lean-burn engines, significantly improves the fuel economy, i.e. reducing the CO2 emissions. However, the lean environment in the exhaust gas obstructs the NOx reduction ability of the three-way catalyst, thus emphasizing the need for alternative techniques, where one promising is selective catalytic reduction with hydrocarbons (HC-SCR)....

In this work we study a model of a catalytic reaction among three monomers in order to understand the kinetics of the selective catalytic reduction of NO by ammonia (4NO + 4NH3 + O2 → 4N2 + 6H2O). Our model takes into account the formation of the intermediate species in the global scheme of the reaction. Using the Monte Carlo method we simulated the model on a square lattice and determined its ...

Many coking plants have adopted the process of preheating flue gas to apply medium and low temperature selective catalytic reduction (SCR) denitrification technology, which increases NOx treatment cost, fuel consumption, generates secondary pollutants. Based on unique distribution characteristics coke oven regenerator, this work proposes a method for synergizing SCR inside regenerator remove NO...