A novel kind of organic-inorganic monomer SUASi has been achieved by modifying 5-sulfosalicylic acid (SUA) with 3-aminopropyltrimethoxysilane (APS), subsequently binary and ternary Eu3+ mesoporous hybrid materials with 5-sulfosalicylic acid (SUA)-functionalized SBA-15 and 1,10-phenanthroline (phen) are synthesized by co-condensation of SUASi and TEOS in the presence of Eu3+ complex and Pluronic...

The chiral selectivities were altered and high diastereo- and enantio-selectivities of the products were obtained in water medium without adding acid co-catalysts when a primary-tertiary diamine catalyst was immobilized on mesoporous SBA-15 to form a recyclable catalyst for the direct asymmetric aldol reaction of cyclohexanone with p-nitrobenzaldehyde.

Unlike most conventional anode materials, the newly developed TiNb2O7 (TNO) does not form a solid electrolyte interface (SEI) layer, which makes it safe for high power requiring lithium-ion batteries. In this paper, we demonstrated an SBA-15 confined synthetic approach to prepare TNO nanoparticles (S-TNO) with a small particle size around 10 nm and a large BET surface area of 79.5 m(2) g(-1). I...

Ordered mesoporous SBA-15 analogs with different Si/Al ratios were successfully prepared in a two-step process from self-assembly of ZSM-5 nanoseeds at high temperature in mildly acidic media (473 K, pH 3.5). The obtained products were characterized as SAXS, XRD, N₂ sorption, FTIR, TEM, NH₃-TPD, AAS and ICP. The results show that the initial Si/Al molar ratio of ZSM-5 precursors strongly affect...

The ability of a number of mesoporous silica materials (SBA-15, SBA-3, and MCM-48) to immobilize polyphenol oxidase (PPO) at different pH has been tested. Pore size and volume are the structural characteristics with higher influence on the PPO immobilization. Mesoropous material SBA-15 adsorbs a larger quantity of PPO at pH 4.00 and offers an inhibition of enzymatic activity close the 50% in ap...

Amine-modified mesoporous SBA-15 adsorbent has been prepared by impregnation method using tetraethylenepentamine. The samples of this modified SBA-15 have been characterized by small angle X-ray scattering (SAXS), Scanning electron microscopy (SEM), Nitrogen adsorption-desorption isotherm and FT-IR. The adsorption capacity of CO2 on unmodified and modified samples were measured at high pressure...