Certain phenolic compounds represent a distinct class of Photosystem (PS) II Q(B) site inhibitors. In this paper, we report a detailed study of the effects of 2,4,6-trinitrophenol (TNP) and other phenolic inhibitors, bromoxynil and dinoseb, on PS II energetics. In intact PS II, phenolic inhibitors bound to only 90-95% of Q(B) sites even at saturating concentrations. The remaining PS II reaction...