نتایج جستجو برای: room temperature ionic liquids

تعداد نتایج: 562639  

Journal: :Physical chemistry chemical physics : PCCP 2015
Olga Russina Fabrizio Lo Celso Alessandro Triolo

Among the most spectacular peculiarities of room temperature ionic liquids, their mesoscopically segregated structural organization keeps on attracting attention, due to its major consequences for the bulk macroscopic properties. Herein we use molecular dynamics simulations to explore the nm-scale architecture in 1-octyl-3-methylimidazolium tetrafluoroborate, as a function of pressure. This stu...

2001
Kenneth R. Seddon Annegret Stark María-José Torres

We report here the first systematic study of the effect of impurities and additives (e.g., water, chloride, and cosolvents) on the physical properties of room-temperature ionic liquids. Remarkably, it was discovered that the viscosity of mixtures was dependent mainly on the mole fraction of added molecular solvents and only to a lesser extent upon their identity, allowing viscosity changes duri...

Journal: :Science 2002
Wen Lu Andrei G Fadeev Baohua Qi Elisabeth Smela Benjamin R Mattes Jie Ding Geoffrey M Spinks Jakub Mazurkiewicz Dezhi Zhou Gordon G Wallace Douglas R MacFarlane Stewart A Forsyth Maria Forsyth

pi-Conjugated polymers that are electrochemically cycled in ionic liquids have enhanced lifetimes without failure (up to 1 million cycles) and fast cycle switching speeds (100 ms). We report results for electrochemical mechanical actuators, electrochromic windows, and numeric displays made from three types of pi-conjugated polymers: polyaniline, polypyrrole, and polythiophene. Experiments were ...

Journal: :Advanced materials 2012
Verner K Thorsmølle Daniel Topgaard Jan C Brauer Shaik M Zakeeruddin Björn Lindman Michael Grätzel Jacques-E Moser

Salts in the liquid phase at room temperature–ionic liquids– have recently received increased attention due to their unique properties.[1] These include high ionic conductivity, high thermal and chemical stability, broad electrochemical windows, non-volatility and non-flammability. These important properties make them versatile alternatives to conventional solvent-based systems, and their poten...

2012
Oliviero Andreussi Nicola Marzari

Room Temperature Ionic Liquids (RTILs) have attracted much attention in the scientific community in the past decade due the their novel and highly customizable properties. Nonetheless their high viscosities pose serious limitations to the use of RTILs in practical applications. To elucidate some of the physical aspects behind transport properties of RTILs, extensive classical molecular dynamics...

In recent years there has been a great deal of attention paid by researchers in investigating ionic liquids (ILs) mainly due to the tremendous potential that ionic liquids have in reaction and separation technology. Sonic speed is an important thermodynamic property of ionic liquids (ILs) and always chosen as a source to determine other properties. A database for the sonic speed of pure ILs cre...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه شیراز - دانشکده علوم 1391

in this thesis protic and aprotic ammonium-based ionic liquids were synthesized and their surface tensions were measured in the range of 298-373k. the protics are alkyl ammonium-based ils with the carboxylate (formate, acetate, propionate) anion and aprotics are quaternary ammonium-based ils with bis(trifluoromethylsulfonyl)imide anion. capillary rise method was used for surface tension measure...

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