We determine which (ordinary) Riordan arrays are the coefficient arrays of a family of orthogonal polynomials. In so doing, we are led to introduce a family of polynomials, which includes the Boubaker polynomials, and a scaled version of the Chebyshev polynomials, using the techniques of Riordan arrays. We classify these polynomials in terms of the Chebyshev polynomials of the first and second ...