A novel design as well as a straight-forward synthesis for a photoswitchable guanidine catalyst is reported. Intense studies of the photochromic properties demonstrated the reversible switchability of its photosensitive azobenzene moiety. Its activity in the ring-opening polymerization (ROP) of rac-lactide was investigated as well. The obtained results are discussed, and an additional guanidine...

Recently testing of Quantum-dot Cellular Automata (QCA) Circuits has attracted a lot of attention. In this paper, QCA is investigated for testable implementations of reversible logic. To amplify testability in Reversible QCA circuits, a test method regarding to Built In Self Test technique is developed for detecting all simulated defects. A new Reversible QCA MUX 2×1 desig...

The importance of DNA for living creatures is a very well known fact. Furthermore, the rich structure and knowing the role of the structure of DNA has led the researchers to the direction where the structure of DNA can be realized in computing processes and computer related technologies. Recent studies show that DNA can storage data as a big digital memory and can be a good tool for error corre...

Let R be a commutative ring with nonzero identity. A proper ideal I of is said to 1-absorbing prime if xyz ∈ for some nonunits x, y, z R, then xy or I. It well known that ⇒ primary semi-primary ideal, is, the class ideals comes between classes and ideals. Also, above right arrows are not reversible. In this article, we characterize rings over which every prime. by comparing other classical such...

We study a one-dimensional lattice gas "dynamical geometry model" in which local reversible interactions of counter-rotating groups of particles on a ring can create or destroy lattice sites. We exhibit many periodic orbits and show that all other solutions have asymptotically growing lattice length in both directions of time. We explain why the length grows as squareroot of t in all cases exam...

Enantiopure (R,R) and (S,S)-dimethyl-bis(ethylenedithio)tetrathiafulvalene monosulfones have been synthesized by the aerial oxidation of the chiral dithiolates generated from the propionitrile-protected precursors. Both enantiomers crystallize in the orthorhombic chiral space group P212121. They show a boat-type conformation of the TTF moiety, a rather rigid dithiin sulfone ring and the methyl ...

Thiophene-S,S-dioxidized diarylethenes introducing bulky substituents at the reactive positions were newly synthesized. The diarylethenes showed reversible photochromism, whereas the photocycloreversion reaction was suppressed by thiophene-oxidation. The diarylethene closed-ring isomers having secondary alkyl groups at the reactive positions were found to undergo thermal bleaching reactions whi...

The development of a ligand-assisted Pd-catalyzed C–H alkenylation of aliphatic amines is reported. Our studies indicated that an amino-acid-derived ligand renders the C–H bond activation step reversible and promotes the traditionally difficult alkenylation process. The C(sp)–H alkenylation proceeds through a 5-membered-ring cyclopalladation pathway that allows access to complex aliphatic heter...

In molecular structure, both UQs and MKs consist of a polar head group and a hydrophobic side chain. The latter part provides the molecules with a lipid-soluble character to allow them to perform vital functions in membrane lipid bilayers, whereas the former group enables interaction with membrane proteins. The quinone ring of the head group has a crucial activity by a two-step reversible reduc...

The crystal structure of poly(7-heptalactone) (PHL) is presented. PHL has been synthesized by a combination ring-opening polymerization η-heptalactone and reversible addition–fragmentation chain transfer using diphenyl phosphate as catalyst. noncommercial available monomer prepared oxidation cycloheptanone. determined analysis the X-ray powder diffraction profiles electron patterns single cryst...