Measured physical spectra often comprise an unknown number of components of known parametric family. A reversible jump Markov chain Monte Carlo (RJMCMC) technique is applied to the problem of estimating the number of components evident in the data jointly with the parameters of the components. The physical model consists of a mixture of components, an additive background, and a convolution with...

Here, we show that E2-EPF ubiquitin carrier protein (UCP) elongated E3-independent polyubiquitin chains on the lysine residues of von Hippel-Lindau protein (pVHL) and its own lysine residues both in vitro and in vivo. The initiation of the ubiquitin reaction depended on not only Lys11 linkage but also the Lys6, Lys48 and Lys63 residues of ubiquitin, which were involved in polyubiquitin chain fo...

Mesoporous Films An oxygen tolerant, DDMAT-initiated and visible-light induced photo electron/energy transfer-reversible addition-fragmentation chain-transfer (PET-RAFT) allows for direct polymer writing in a mesoporous silica thin film. Using commercially available microscope, micrometer scale resolution of the placement three different polymers as well block-copolymer functionalization are ac...

In this work, the combination of different modeling approaches with in-line proton nuclear magnetic resonance (1H-NMR) spectroscopy is used to assist transfer a reversible addition-fragmentation chain (RAFT) polymerization methyl methacrylate micro-scale reactor. This approach then applied find optimal process parameters like temperature or residence time as well best composition reaction mixtu...

Abstract Traditional mechanochemically controlled reversible‐deactivation radical polymerization (RDRP) utilizes ultrasound or ball milling to regenerate activators, which induce side reactions because of the high‐energy and high‐frequency stimuli. Here, we propose a facile approach for tribochemically atom transfer (tribo‐ATRP) that relies on contact‐electro‐catalysis (CEC) between titanium ox...