Au/CeLaOx mixed oxide catalysts containing 0.5 to 1.0 wt% Au were prepared via coprecipitation with HAuCl4, the appropriate nitrate precursors, and either urea or Na2CO3 as the precipitant. BET surface area measurements for the Au/CeLaOx catalysts varied in the range of 16-107 m/g depending on the precipitant, aging time, and calcination conditions. The catalysts were tested for the selective o...

The catalytic oxidation of sulfur dioxide to sulfur trioxide over several binary (MxOy/TiO2) and ternary (V2O5/MXOY/TiO2) supported metal oxide catalysts was systematically investigated. The supported metal oxide components were essentially 100% dispersed as surface metal oxide species, as confirmed by Raman spectroscopy characterization. The sulfur dioxide oxidation turnover frequencies of the...

The field of asymmetric catalysis has progressed rapidly since the early 1980s, as judged by the increasing number of reports each year and the greater frequency with which enantioselective catalysts are employed in industry.1-3 This intense research effort has greatly expanded the variety of reactions that can be performed with good substrate generality and in a highly enantioselective fashion...

ZnO-supported palladium-based catalysts have been shown in recent years to be both active and selective towards the steam reforming of methanol, although they are still considered to be less active than traditional copper-based catalysts. The activity of PdZn catalysts can be significantly improved by supporting them on alumina. Here we show that the Pd/ZnO/Al2O3 catalysts have better long-term...

Metal nanoparticles are promising catalysts for dye degradation in treating wastewater despite the challenges of recycling and stability. In this study, we have introduced a simple way to prepare Au@polypyrrole (PPy)/Fe3O4 catalysts with Au nanoparticles embedded in a PPy/Fe3O4 capsule shell. The PPy/Fe3O4 capsule shell used as a support was constructed in one-step, which not only dramatically ...

In meeting the need for environmental remediation in wastewater treatment and the development of popular sulfate-radical-based advanced oxidation processes (SR-AOPs), a series of Co/Fe-based catalysts with confirmed phase structure were prepared through extended soft chemical solution processes followed by atmosphere-dependent calcination. Powder X-ray diffraction (XRD), scanning electron micro...

This article describes new selectivities for Grubbs’ first and second generation catalysts when occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS). Occlusion of catalysts in mm-sized slabs of PDMS is accomplished by swelling with methylene chloride then removing the solvent under vacuum. The catalysts are homogenously dissolved in PDMS yet remain catalytically active. Many substrat...

The main disadvantage of biodiesel is its high price. The price of biodiesel depends on various factors such as the price of oil, methanol, catalyst, and labor. Among dif-ferent economic factors, oil accounts for the largest share of input costs of biodiesel production. In this study, first, suitable heterogeneous catalysts were identified for biodiesel production. Several studies were carried ...

Utilization of active and stable catalyst could have enormous advantages in industrial application of biogas reforming. In order to achieve this goal, the effects of Cu and Co as promoters were investigated over physical-chemical properties of Ni/Al2O3-ZrO2 catalyst in reforming of biogas. The sequential impregnation was used for preparation of catalysts. The catalysts were characterized using ...

EEthylene polymerization catalysts became available in an enormous variety. The challenge in this research is to find catalysts that are able to connect ethylene molecules in such a way that not only linear chains are produced but variations like branched materials that possess very interesting mechanical properties like linear low density polyethylene (LLDPE). In this contribution, three diffe...