Ionic PNIPAm microgels were synthesized by free-radical precipitation polymerization using 2-acrylamido-2-methyl-1-propanesulfonic acid as an ionic co-monomer (references 7 and 9 of the paper), and fluorescently labelled with the covalently linked dye methacryloxyethyl thiocarbamoyl rhodamine B. N, N-methylene-bis-acrylamide was used as a cross-linker (with a 2.74 mol% cross-link density) and p...

Combined in situ X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) studies have been conducted to follow gold structural changes of low-content (<1%Au) gold-ceria catalysts in water-gas shift (WGS) reaction tests at 100 and 200 °C; and after heating the used catalysts in oxygen gas at 150 °C. Gold in the fresh (400 °C-calcined) material was atomic...

Although Ca(OH)2 is one of the oldest art and building material used by mankind, little is known about its nanostructural and colloidal characteristics that play a crucial role in its ultimate performance as a binder in lime mortars and plasters. In particular, it is unknown why hydrated lime putty behaves as an irreversible colloid once dried. Such effect dramatically affects the reactivity an...

conclusions in conclusion, the suspension containing veegum 1%, sodium carboxy methyl cellulose 1%, glycerine 0.2%, sodium citrate 0.3% and sorbitol 20 % was chosen as the most physically stable formulation. results according to the results, glycerin (0.2%) and sodium citrate (0.3%) had the best effect on the suspension stability as wetting and flocculating agents, respectively. rheological pro...

We report a method for the preparation of colloidal ZnO-diluted magnetic semiconductor quantum dots (DMS-QDs) by alkaline-activated hydrolysis and condensation of zinc acetate solutions in dimethyl sulfoxide (DMSO). Mechanistic studies reveal that Co(2+) and Ni(2+) dopants inhibit nucleation and growth of ZnO nanocrystals. In particular, dopants are quantitatively excluded from the critical nuc...

ABSTRACT Aerosol size information is very important for risk estimation of radon exposure. Size measurements of aerosol particles attaching radon progeny were made by using the Dekati's ELPI (Electrical Low Pressure Impactor), and its attachment function was determined. The impactor, which covers a wide size range from 0.03 to 10 μm in diameter, gives number size distribution in real time by an...

As the youngest in the graphene family, fluorographene has received numerous expectations from the scientific community. Investigation of fluorographene is similar to graphene and graphene oxide, wherein fabrication is an importance subject in the infancy stage. Fluorographene produced by the currently existing protocols, however, could only disperse in a limited number of solvents, and the dis...

A thermosensitive ophthalmic hydrogel (TSOH) - fluid at 4°C (instillation temperature), semisolid at 35°C (eye temperature), which coupled the dosing accuracy and administration ease of eyedrops with the increased ocular bioavailability of a hydrogel - was prepared by gelling a chitosan hydrochloride (ChHCl) solution (27.8 mg/mL) medicated with 1.25 mg/mL 5-fluorouracil (5-FU) with β-glyceropho...

A critical component of preventing the spread of vector borne diseases such as Chagas disease are door-to-door campaigns by public health officials that implement insecticide application in order to eradicate the vector infestation of households. The success of such campaigns depends on adequate household participation during the active phase as well as on sufficient follow-up during the survei...

Interactive surface chemistry of CO2 and NO2 on BaOx/Pt(111) model catalyst surfaces were investigated via X-ray photoelectron spectroscopy (XPS) and temperature-programmed desorption (TPD) techniques with a particular emphasis on the competition between different adsorbates for the catalytic adsorption sites and adsorbateinduced morphological changes. After NO2 adsorption, nitrated BaOx/Pt(111...