A reaction kinetic model of the bipolar membrane interface in the bipolar membrane fuel cell (BPMFC) was proposed based on the p-n junction theory and chemical reaction kinetics. It verified the self-humidification feasibility of the BPMFC successfully.

[1] This paper presents the development and illustration of a numerical model of reactionbased geochemical and biochemical processes with mixed equilibrium and kinetic reactions. The objective is to provide a general paradigm for modeling reactive chemicals in batch systems, with expectations that it is applicable to reactive chemical transport problems. The unique aspects of the paradigm are t...

In this research work the reaction kinetics of the molybdate-catalyzed epimerization of glucose in aqueous solutions has been mathematical modeled and investigated. Experiments were performed in a microstructured reactor in continuous flow regime. The results show high yield of mannose in the range between 21-27.1%, which exceeds the actual literature data with a ratio 3:1. The kinetic model is...

A theoretical model of a surface electrode reaction coupled with a preceding chemical reaction (surface CE electrode mechanism) is theoretically studied under conditions of square-wave voltammetry. The position and the shape of the theoretical voltammograms are function of the redox kinetic parameter k 1⁄4 ks f where ks is the standard electron exchange rate constant and f is the frequency of t...

The pseudo-first order rate constants and activation parameters have been determined using two methods, constant-temperature kinetic (CTK) and variable temperature kinetic (VTK), for the oxidative addition reactions of [Pt2Me2(C^N)2(µ-dppf)], (1a, C^N = deprotonated 2-phenylpyridine (ppy); 1b, C^N = deprotonated benzo[h]quinoline (bhq)) with MeI. The results obtained from VTK method are in agre...

Kinetic models provide the means to understand and predict the dynamic behaviour of enzymes upon different perturbations. Despite their obvious advantages, classical parameterizations require large amounts of data to fit their parameters. Particularly, enzymes displaying complex reaction and regulatory (allosteric) mechanisms require a great number of parameters and are therefore often represen...

in this research work, the dissolution of chalcopyrite was investigated under atmospheric pressure, with sulfate media at low temperatures, in 30°c to 50°c. in the galvanic interaction between chalcopyrite and pyrite, pyrite is used as a leaching catalyst. effects of different parameters such as temperature, stirring speed, pyrite to chalcopyrite ratio, particle size, and solution potential wer...

A global kinetic analysis of a general zymogen activation model, where not only the activating but also the activated enzyme suffer an irreversible inhibition is presented. A reaction in which the enzyme acts upon a substrate is coupled to monitor the process. In addition, we determined the corresponding kinetic equations for a number of particular cases of the general model studied. Finally, a...

Kinetic modeling of batch reactions monitored by in situ spectroscopy has been shown to be a helpful method for developing a complete understanding of reaction systems. Much work has been carried out to demonstrate the ability to model dissolution, reaction, and crystallization processes separately; however, little has been performed in terms of combining all of these into one comprehensive kin...