Ir-catalyzed enantioselective [2 + 2 + 2] cycloaddition of tetraynes or an octayne with monoalkynes proceeded to give helically-chiral quinquearyl and noviaryl compounds, which respectively have four and eight consecutive axial chiralities, in an almost enantiomerically pure form.

gracilariopsis persica (rhodophyta) is one of the most abundant algae, introduced newly from the indian ocean. in this study,   the main sterols of the algae have been isolated and identified. separation and purification of the compounds was carried out on silica gel and sephadex lh20 column chromatography (cc) and high performance liquid chromatography (hplc) to obtain five pure compounds 1-5....

Antrodia camphorata is a unique mushroom of Taiwan, which has been used as a traditional medicine for protection of diverse health-related conditions. In an effort to translate this Eastern medicine into Western-accepted therapy, a great deal of work has been carried out on A. camphorata. This review discusses the biological activities of the crude extracts and the main bioactive compounds of A...

BACKGROUND Obesity and Type 2 diabetes have reached epidemic status worldwide. Wild lowbush blueberry (Vaccinium angustifolium Aiton) is a plant of the North American Aboriginal traditional pharmacopeia with antidiabetic potential, especially when it is fermented with Serratia vaccinii. METHODS A phytochemical fractionation scheme was used to identify potential bioactive compounds as confirme...

Streptomyces aureofaciens growth in chemically defined medium is actively associated with the secretion of low-molecular-weight nucleic acid-related substances and is linked to low availability of phosphate. Thirteen pure compounds were isolated, of which seven were identified.

Trans–cis isomerization was investigated in a room temperature liquid crystal mixture of two azoxybenzene compounds. Experiments were performed on isolated molecules in dilute solutions and on the liquid crystal phase composed of the pure compounds. The absorption spectra of the trans and cis isomers were found to be similar to those of azobenzene compounds, as were the birefringence and order ...

Cyclic dianions are considered to be useful synthons for the construction of a wide variety of cyclic organic compounds and organometallic complexes. However, reported patterns of substituted cyclic dianions are very much limited owing to the lack of synthetic methods. Furthermore, information on the structure of dianion species is very rare, which also to some extent blocks the development of ...

Legumes and the polyphenolic compounds present in them have gained a lot of interest due to their beneficial health implications. Dietary polyphenolic compounds, especially flavonoids, exert antioxidant properties and are potent inhibitors of xanthine oxidase (XO) activity. XO is the main contributor of free radicals during exercise but it is also involved in pathogenesis of several diseases su...