primary mgcl2.3.3etoh adduct (pct1) was prepared by melt quenching method and then submitted into a programmed thermal dealcoholation project using a fluidized bed reactor. during thermal dealcoholation program, different mgcl2.netoh support samples with n= 3.0, 2.7, 2.4, and 2.1 were selected and named as pct2 to pct5, respectively. structural analysis of the support samples showed a significa...

Poly (propylene fumarate) (PPF), a linear unsaturated polyester consisting of alternating propylene glycol and fumaric acid units, can be cured in vivo to fill the skeletal defects with minimal surgical intervention. Many different methods have been reported for synthesizing PPF, but none of them gives a clear method. The present paper introduces two new methods in PPF synthesis: Modified reflu...

poly (propylene fumarate) (ppf), a linear unsaturated polyester consisting of alternating propylene glycol and fumaric acid units, can be cured in vivo to fill the skeletal defects with minimal surgical intervention. many different methods have been reported for synthesizing ppf, but none of them gives a clear method. the present paper introduces two new methods in ppf synthesis: modified reflu...

Post-polymerization modification offers a facile and effective tool for adapting polymer properties. However, it has not been applied to poly(propylene carbonate) (PPC) as traditional PPC lacks sufficient functional groups along the chain. In present work, first time, hydroxyl-functionalized prepared used construct PPC-brush cross-linked gels through post-polymerization approach. PPC-brushes in...

New aluminium complexes containing bis-BTP ligands (BTP = N,O-bidentate benzotriazole phenoxide) were synthesized and structurally characterized. Amine elimination of Al(NMe2)3 with (R)BTP-H ligands ((CMe2Ph)BTP-H = 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol, (t-Bu)BTP-H = 2-(2H-benzotriazol-2-yl)-4,6-di-tert-butylphenol and (TMCl)BTP-H = 2-tert-butyl-6-(5-chloro-2H-benzotri...

Ethylene-propylene-diene rubbers (EPDM) are one of the most important polyolefin materials widely commercialized and used in various industries recent years. The production EPDM is based solely on catalytic coordination polymerization processes. development new catalysts processes for synthesis has expanded range products their manufacturing terms energy efficiency, processability, environmenta...

several types of hybrid catalysts are made through mixing of 4th generation ziegler-natta (zn) and (2-phind)2zrcl2metallocene catalysts using triethylaluminum (tea) as coupling agent. response surface methodology (rsm)is used to evaluate the interactive effects of different parameters including amounts of metallocene and tea andtemperature on metallocene loading. analyzing the amounts of al and...

The interaction of the external donor (propyltrimethoxysilane - PTMS) with titanium-magnesium catalysts (TMCs) containing dibutylphthalate (DBP) as internal donor, which were prepared in different ways, was studied by chemical analysis and infrared diffuse reflectance spectroscopy (DRIFTS). The chemical composition of the catalysts after their interaction with heptane solutions of PTMS, PTMS/Al...