The Aluminum Hypothesis, the idea that aluminum exposure is involved in the etiology of Alzheimer disease, dates back to a 1965 demonstration that aluminum causes neurofibrillary tangles in the brains of rabbits. Initially the focus of intensive research, the Aluminum Hypothesis has gradually been abandoned by most researchers. Yet, despite this current indifference, the Aluminum Hypothesis con...

It is well known that main group metal ions with an s* electron configuration form a large variety of polynuclear coordination compounds [l]. Recently it has been suggested that in these compounds a weak metal-metal bonding may exist which is achieved by sp orbital mixing [2]. In particular, calculations on Tl+ clusters were used to support this idea. Unfortunately, the metal-metal interaction ...

Aqueous core/polymer shell microcapsules with mononuclear and polynuclear core morphologies have been formed by internal phase separation from water-in-oil emulsions. The water-in-oil emulsions were prepared with the shell polymer dissolved in the aqueous phase by adding a low boiling point cosolvent. Subsequent removal of this cosolvent (by evaporation) leads to phase separation of the polymer...

Aluminum has been implicated in several neurodegenerative conditions including Alzheimer's disease. Because the mammalian olfactory system has an unusual capacity for the uptake and transneuronal spread of inhaled substances such as aluminum, whole cell recording techniques were used to examine the actions of aluminum on basic membrane properties and amino acid receptors on rat olfactory bulb m...

Mononuclear and polynuclear chelates of potassium picolinoyldithiocarbazate (KHPcDC) with Mn(II), Fe(ll1), Fe(II), Co(Il), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), Pd(II) and U(VI)O2 have been prepared and characterized by chemical and thermal (TG, DTG, DTA) analyses, molar conductivities, spectral (UV-Visible, IR, NMR, ESR) and magnetic moment measurements. The molar conductivities of the compl...

We consider a discrete polynuclear growth (PNG) process and prove a functional limit theorem for its convergence to the Airy process. This generalizes previous results by Prähofer and Spohn. The result enables us to express the F1 GOE Tracy-Widom distribution in terms of the Airy process. We also show some results, and give a conjecture, about the transversal fluctuations in a point to line las...

We study statistical properties of a continuum model of polynuclear surface growth on an infinite substrate. We develop a self-consistent mean-field theory which is solved to deduce the growth velocity and the extremal behaviour of the coverage. Numerical simulations show that this theory gives an improved approximation for the coverage compared to the previous linear recursion relations approa...

We study a variant of poly-nuclear growth where the level boundaries perform continuous-time, discrete-space random walks, and study how its asymptotic behavior is affected by the presence of a columnar defect on the line. We prove that there is a non-trivial phase transition in the strength of the perturbation, above which the law of large numbers for the height function is modified.

The aqua ions of palladium(II) and platinum(II) undergo extremely slow hydrolysis in strongly acidic aqueous solution, resulting in polynuclear complexes. The size and structures of these species have been determined by EXAFS and small angle X-ray scattering, SAXS. For palladium(II), the EXAFS data show that the Pd-O and Pd···Pd distances are identical to those of crystalline palladium(II) oxid...

Two new polynuclear heterometallic cluster complexes with [Mn(III)(3)M(II)Na] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [Mn(III)Ca(II)Na] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry.