We study the translocation process of a polymer in the absence of external fields for various pore diameters b and membrane thickness L. The polymer performs Rouse and reptation dynamics. The mean translocation time (tau(t)) that the polymer needs to escape from a cell and the mean dwell time (tau(d)) that the polymer spends in the pore during the translocation process obey scaling relations in...

We introduce a model for prediction the behavior of electrodes which modified withcarbon nanotubes in a polymer medium. These kinds of polymer composites aredeveloped in recent years, and experimental data for its percolation threshold isavailable. We construct a model based on percolation theory and fractal dimensionsand using experimental percolation threshold for calculating the moments of c...

Translocation of a polymer out of curved surface or membrane is studied via mean first passage time approach. Membrane curvature gives rise to a constraint on polymer conformation, which effectively drives the polymer to the outside of membrane where the available volume of polymer conformational fluctuation is larger. Considering a polymer release out of spherical vesicle, polymer translocatio...

Ž . Several polymer-coated and polymer-grafted multi-walled carbon nanotubes MWNTs were synthesized and characterized using TEM and HRTEM. The polymer-coated or polymer-grafted MWNTs formed stable solutions in DMF. Their nonlinear optical properties were investigated using 532 nm nanosecond laser pulses. These polymer–MWNT composites still possess strong nonlinear optical properties. q 2000 Els...

Nanoparticle-polymer composites, or polymer-nanoparticle composites (PNCs), exhibit unusual mechanical and dynamical features when the particle size approaches the random coil dimensions of the host polymer. Here, we harness favourable enthalpic interactions between particle-tethered and free, host polymer chains to create model PNCs, in which spherical nanoparticles are uniformly dispersed in ...

This paper reviews recent progress in the studies on polymer surfaces/interfaces using sum frequency generation (SFG) vibrational spectroscopy. SFG theory, technique, and some experimental details have been presented. The review is focused on the SFG studies on buried interfaces involving polymer materials, such as polymer–water interfaces and polymer–polymer interfaces. Molecular interactions ...

One of the challenges in polymer science has been to prepare large-polymer single crystals. We demonstrate a visible light-triggered quantitative topochemical polymerization reaction based on a conjugated dye molecule. Macroscopic-size, high-quality polymer single crystals are obtained. Polymerization is not limited to single crystals, but can also be achieved in highly concentrated solution or...

We have investigated conformational properties of a linear semiflexible homopolymer chain in the bulk and adsorption desorption behaviour in the presence of an attractive impenetrable curved surface using lattice models. Since, it is understood that the essential physics associated with the conformational behavior of such polymer chains can be derived from a model of a self avoiding walk (SAW) ...