Capillary condensation in nanoporous anodic aluminum oxide presenting not interconnected pores with controlled modulations is studied using adsorption experiments and molecular simulations. Both the experimental and simulation data show that capillary condensation and evaporation are driven by the smallest size of the nanopore (constriction). The adsorption isotherms for the open and closed por...

In the present research, the potential of two biochars produced by the thermal decomposition of wheat straw (BCS) and wicker (BCW) for Cr(VI) ions removing from wastewater was investigated. The pH and the presence of chlorides and nitrates were also investigated. The Freundlich and Langmuir models were applied for the characterization of adsorption isotherms. The Langmuir model has better fitti...

A new colorimetric method for determining the surface-accessible acidic lignin hydroxyl groups in lignocellulose solid fractions was developed. The method is based on selective adsorption of Azure B, a basic dye, onto acidic hydroxyl groups of lignin. Selectivity of adsorption of Azure B on lignin was demonstrated using lignin and cellulose materials as adsorbents. Adsorption isotherms of Azure...

Monte Carlo simulations were employed to gain insight on HCN adsorption mechanism on LTA zeolites with different alkali metal cations, Li, Na, and K. Adsorption isotherms were calculated at four different temperatures at and above the normal boiling point of HCN. Results show that adsorption capacity depends on the type of the extraframework cation and Li-LTA showed the highest HCN adsorption c...

We present a non-destructive, reusable apparatus with which to measure physical adsorption isotherms of intact porous membranes. We developed a two-piece sample container to make reliable sorption measurements of porous membranes, the properties of which may differ from those of powders due to crystal intergrowth. This novel system employs a resealable container that can be immersed in a cryoge...

An extension of the Lagrange{Galerkin approach is developed for advection-dominated problems with nonlinear adsorption, either being in equilibrium or in non{equilibrium, possibly with isotherms of the Freundlich type. The scheme should be feasable also for the hyperbolic limit case. The basic problems to deal with are the possibility of non{unique characteristics due to the nonlinear isotherms...

Pure silica zeolites are potentially hydrophobic and have therefore been considered to be interesting candidates for separating alcohols, e.g., 1-butanol, from water. Zeolites are traditionally synthesized at high pH, leading to the formation of intracrystalline defects in the form of silanol defects in the framework. These silanol groups introduce polar adsorption sites into the framework, pot...

The present research investigates the ability of graphene oxide nanosheets for treatment of dairy wastewater, using In Situ Sludge Magnetic Impregnation” (ISSMI) to separate sludge after adsorption process. To increase the interaction between magnetic nanoparticles and graphene oxide, the former has been functionalized, using 3-Aminopropyl triethoxysilane, with the synthesized graphene oxide an...

Adsorption isotherms of 10 pesticides and their biodegradation intermediates on clay minerals and soils were investigated to predict the fate of pesticides in the environment. The adsorption isotherms were expressed by the Freundlich isotherm equation. Pentachloronitrobenzene, 2,4,6-trichlorophenyl-4′-nitrophenylether, and various intermediates were highly adsorbed on soils, although isoprothio...